Publications

2009-2013

REFEREED PUBLICATIONS

281. Shu, C.; Xu, W.; Slebodnick, C.; Champion, H.; Fu, W.; Cai, T.; Reid, J. E.; Azurmendi, H.; Wang, C.-R.; Harich, K.; Gibson, H. W. Dorn, H. C. Synthesis and Structure of PCBM Analogues from TNT Metallofullerenes, Org. Lett. 2009, 11, ASAP, March 23.

282. Gibson, H. W.; Farcas, A.; Jones, J. W.; Ge, Z.; Huang, F.; Vergne M.; Hercules, D. M. Supramacromolecular Self-Assembly: Chain Extension, Star And Block Polymers Via Pseudorotaxane Formation From Well-Defined End-Functionalized Polymers, J. Polym. Sci., Polym. Chem. Ed. 2009, 47, in press.

283. C. Shu, F. D. Corwin, J. Zhang, J. E. Reid, M. Sun, W. Xu, J. H. Sim, C.-R. Wang, P. P. Fatouros, A. R. Esker, H. W. Gibson, H. C. Dorn, Preparation ofa New Gadofullerene-Based Magnetic Resonance Imaging Contrast Agent with High 1H Relaxivity, Bioconj. Chem., 2009, 18, in press.

REVIEWS, BOOKS, BOOK CHAPTERS

23. Niu, Z,; Gibson, H. W. Polycatenanes, Chem. Rev. 2009, 109, submitted January 6.

24. Olmstead, M. M.; Balch, A. L.;Pinzon, J. R.; Echegoyen, L.; Gibson, H. W.; Dorn, H. C. New Endohedral Metallofullerenes: Trimetallic Nitride Endohedral Fullerenes, invited chapter in Chemistry of Nanocarbons, Akasaka, T., ed., submitted April 5, 2009.

PREPRINTS, UNREFEREED PUBLICATIONS

95. M. Lee, H. W. Gibson, U-H. Choi, R. Colby, Room-Temperature Ionic Liquid Monomers and Their Polymers: Synthesis and Characterization of Poly(imidazolium acrylate)s, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2009, 50(2), ???-??.

96. M. A. Rouser, A. M.-P. Pederson, Z. Niu, D. V. Schoonover, H. W. Gibson, Synthesis and Characterization of a Slip-Link Polyrotaxane, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2009, 50(2), ???-??.

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2004-2008

REFEREED PUBLICATIONS

233. Guzy, M.; Davis, R. M.; Neyman, P. J.; Brands, C.; Heflin, J. R.; Gibson, H. W.; Van Cott, K. E. Self-Assembled Oganic Films: Covalent/Ionic Self-Assembly for Second-Order Nonlinear Optical Materials, Encyclopedia of Nanoscience and Nanotechnology, M. Dekker, New York, 2004, pp. 3471-3480.

234. Jones, J. W.; Huang, F.; Bryant, W. S.; Gibson H. W. A Cautionary Note Regarding the Investigation of Supramolecular Complexes involving Secondary Ammonium Salts in Acetone, Tetrahedron Lett. 2004, 45, 5961-5963.

235. Gibson, H. W.; Nagvekar, D. S.; Yamaguchi, N.; Bhattarcharjee, S.; Wang, H.; Vergne, M.; Hercules, D. M. Polyrotaxanes Formed by In Situ Threading During Polymerization of Functional Macrocycles.  Poly(amide crown ether)s Based on Bis(5-carboxy-1,3-phenylene)-(3x+2)-crown-x Ethers, Macromolecules 2004, 37,  7514-7529.

236. Huang, F; Zhou, L.; Jones, J. W.; Gibson, H. W.; Ashraf-Khorassani, M.  Formation of Pseudorotaxane Complex Dimers Driven by Dipole-Dipole and Face-to-Face p-Stacking Interactions, Chem. Commun. 2004, 2670-2671.

237. Huang, F.; Gibson, H. W. Formation of a Reversible Supramolecular Hyperbranched Polymer from Self-Organization of an AB2 Monomer Containing a Crown Ether and Two Paraquat Moieties, J. Am. Chem. Soc. 2004, 126, 14738-14739.

238. Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Ashraf-Khorassani, M; Gibson, H. W. Synthesis of a Symmetric Cylindrical Bis(crown ether) Host and Its Complexation with Paraquat, J. Org. Chem. 2005, 70, 809-813.

239. Huang, F.; Nagvekar, D. S.; Slebodnick, C.; Gibson, H. W. A Supramolecular Triarm Star Polymer from a Homotritopic Tris(Crown Ether) Host and a Complementary Monotopic Paraquat-Terminated Polystyrene Guest by a Supramolecular Coupling Method, J. Am. Chem. Soc. 2005, 127, 484-485.

240. Huang, F.; Guzei, I. A.; Jones, J. W.; Gibson, H. W. Remarkably Improved Complexation of a Bisparaquat by Formation of a Pseudocryptand-Based [3]Pseudorotaxane, Chem. Commun. 2005, 1693-1695.

241. Huang, F.; Gibson, H. W. A Supramolecular Poly[3]pseudorotaxane by Self-Assembly of a Homoditopic Cylindrical Bis(crown ether) Host and a Bisparaquat Derivative,Chem. Commun . 2005, 1695-1698.  

242. Gibson, H. W.; Ge, Z.; Huang, F.; Jones, J. W.; Lefebvre, H.; Vergne, M. J.; Hercules, D. M. Syntheses and Model Complexation Studies Of Well-Defined Crown Terminated Polymers, Macromolecules 2005, 38, 2626-2637.

243. Huang, F.; Switek, K. A.; Zakharov, L. N.; Fronczek, F.; Slebodnick C.; Lam, M.; Golen, J. A.; Bryant, W. S.; Mason, P.; Ashraf-Khorassani, M.; Rheingold, A. L.; Gibson, H. W. Cryptands, Powerful Hosts for Paraquat Derivatives, J. Org. Chem. 2005, 70, 3231-3241.

244. Gibson, H. W.; Wang, H.; Bonrad, K.; Jones, J. W.; Slebodnick, C.; Habenicht, B.; Lobue, P. Regioselective Routes to Disubstituted Dibenzo Crown Ethers and Their Complexations, Org. Biomol.  Chem. 2005, 3, 2114-2121.

245. Huang, F.; Zakharov, L. N.; Bryant, W. S.; Rheingold, A. L.; Gibson, H. W. Promotion of Host Folding during the Formation of a Taco Complex, Chem. Commun. 2005, 3268-3270.

246. Cai, T.; Ge, Z.; Iezzi, E. B.; Glass, T. E.; Harich, K.; Gibson, H. W.; Dorn, H. C. Synthesis and Characterization of the First Trimetallic Nitride Templated Pyrrolidino Endohedral Metallofullerenes, Chem. Commun. 2005, 3594-3596.

247. Huang, F.; Switek, K. A.; Gibson, H. W. pH Controlled Assembly and Disassembly of a Cryptand/Paraquat [2]Pseudorotaxane,Chem. Commun. 2005, 3655-3657.

248. Huang, F.; Slebodnick, C.; Ratliff, A.; Gibson, H. W. Bis(m-phenylene)-32-crown-10/Monopyridinium [2]Pseudorotaxane, Tetrahedron Lett.  2005, 46, 6019-6022.

249. Huang, F.; Fronczek, F. R.; Ashraf-Khorassani, M.; Gibson, H. W. Slow-Exchange C3-Symmetric Cryptand/Trispyridinium Inclusion Complexes: A New Type of Threaded Structure, Tetrahedron Lett. 2005, 46, 6765-6769.

250. Huang, F.; Rheingold, A. L.; Slebodnick, C.; Ohs, A.; Switek, K. A.; Gibson, H. W. [2]Pseudorotaxanes Based on the Cryptand/Monopyridinium Salt Recognition Motif, Tetrahedron2005, 61, 10242-10253.

251. Ge, Z.; Duchamps, J. C.; Cai, T.; Gibson, H. W.; Dorn, H. C. Purification of Endohedral Trimetallic Nitride Fullerenes in a Single, Facile Step, J. Am. Chem. Soc. 2005, 127, 16292-16298.

252. Huang, F.; Slebodnick, C.; Switek, K. A.; Gibson, H. W. Bis(m-phenylene)-32-crown-10-based Cryptand/Diquat Inclusion [2]Complexes, Chem. Commun. 2006, 1929-1931.

253. Heflin, J. R.; Guzy, M. T.; Neyman, P. J.; Gaskins, K. J.; Brands, C.; Wanga, Z.; Gibson, H. W.; Davis, R. M.; Van Cott, K. E.  Efficient, Thermally Stable, Second Order Nonlinear Optical Response in Organic Hybrid Covalent/Ionic Self-Assembled Films, Langmuir 2006, 22, 5723-5727.

254. Cai, T.; Slebodnick, C.; Xu, L.; Harich, K.; Glass, T. E.; Chancellor, C.; Fettinger, J. C.; Olmstead, M. M.; Balch, A. L.; Gibson, H. W.; Dorn,H. C. Pirouette on a Metallofullerene Sphere: Interconversion of Isomers of N-Tritylpyrrolidino Ih Sc3N@C80, J. Am. Chem. Soc. 2006, 128, 6486-6492.

255. Cai, T.; Xu, L.; Anderson, M. R.; Ge, Z.; Zuo, T.; Gibson, H. W.; Dorn, H. C. Enhanced Reactivity Rates of Sc3N@C80 and Lu3N@C80D5h Metallofullerene Isomers: The Importance of the Pyracylene Motif, J. Am. Chem. Soc., 2006, 128, 8581-8589.

256. Huang, F.; Yang, H.; Das, N.; Maran, U.; Arif, A. M.; Gibson, H. W.; Stang, P. J. Incorporating a Flexible Crown Ether into 3-Dimensional Neutral Discrete Supramolecules via Coordination-Driven Self-Assembly, J. Org. Chem. 2006, 71, 6623-6625.

257. Fatouros, P. P.; Corwin, F. D.; Chen, Z.-J.; Broaddus, W. C.; Tatum, J. L.; Ge, Z.; Gibson, H. W.; Kile, J. L.; Leonard, A. P.; Duchamp, J. C.; Dorn, H. C. In Vitro and In Vivo Imaging Studies of a New Gadolinium Endohedral Metallofullerene MRI Contrast Agent, Radiology 2006, 240, 756-764.

258. Huang, F.; Gantzel, P.; Nagvekar, D. S.; Rheingold, A. L.; Gibson, H. W. Taco Grande: A Dumbbell Bis(crown ether)/paraquat [3](Taco Complex), Tetrahedron Lett. 2006, 47, 7841-7844.

259. Huang, F.; Slebodnick, C.; Mahan, E. J.; Gibson, H. W. [3]Pseudorotaxanes Based on the Cryptand/Monopyridinium Salt Recognition Motif, Tetrahedron 2007, 63,2829-2839.

260. Huang, F.; Slebodnick, C.; Switek, K. A.; Gibson, H. W. Inclusion [2]Complexes Based on the Cryptand/Diquat Recognition Motif, Tetrahedron 2007, 63, 2875-2881.

261. Gibson, H. W.; Wang, H.; Slebodnick, C.; Merola, J.; Kassel, S.; Rheingold, A. L. Isomeric 2,6-Pyridino-Cryptands Based on Dibenzo-24-Crown-8, J. Org. Chem. 2007, 72, 3381-3393.

262. Huang, F.; Nagvekar, D. S.; Gibson, H. W. Formation of a Linear Supramolecular Polymer by Self-Assembly of Two Homoditopic Monomers Based on the Bis(m-phenylene)-32-Crown-10/Paraquat Recognition Motif, Macromolecules 2007, 40, 3561-3567.

263. Gibson, H. W.; Berg, M. A. G.; Dickson, J. C.; Lecavalier, P. R.; Wang, H.; Merola, J. S. Diastereomeric Reissert Compounds of Isoquinoline and 6,7-Dimethoxy-3,4-dihydroisoquinoline in Stereoselective Synthesis, J. Org. Chem. 2007, 72, 5759-5770.

264. Cai, T.; Xu, L.; Gibson, H. W.; Dorn, H. C.; Chancellor, C. J.; Olmstead, M. M.; Balch, A. L. Sc3N@C78:Encapsulated Cluster Regio-Control of Adduct Docking on a Ellipsoidal Metallofullerene Sphere, J. Am. Chem. Soc. 2007, 129, 10795-10800.

265. Huang, F.; Jones, J. W.; Gibson, H. W. Competitive Interactions of Ion Paired Salts with Neutral Hosts to Form Non-Ion Paired Complexes, J. Org. Chem. 2007, 72, 6573-6576.

266. Gibson, H. W.; Wang, H.; Chng, C. P.; Glass, T. E.; Schoonover, D.; Zakharov, L. N.; Rheingold, A. L. Synthesis and Conformational Analysis of a Small meta-Cyclophane, Bis(5-carbomethoxy-1,3-phenylene)-14-crown-4, Heteroatom Chem. 2007, 18, 48-54.

267. Zhang, X.; Zhai, C.; Li, N.; Liu, M.; Li, S.; Zhu, K.; Zhang, J.; Huang, F.; Gibson, H. W. Bis(m-phenylene)-32-crown-10-based Cryptand/Diazapyrenium Inclusion [2]Complexes, Tetrahedron Lett. 2007, 48, 7537-7541.

268. Zhang, J.; Huang, F.; Li, N.; Wang, H.; Gibson, H. W.; Gantzel, P.; Rheingold, A. L. Paraquat Substituent Effect on complexation with a Dibenzo-24-crown-8-Based Cryptand, J. Org. Chem. 2007, 72, 8935-8938.

269. Shu, C.; Cai, T.; Xu, L.; Zuo, T.; Reid, J.; Harich, K.; Dorn, H. C.; Gibson, H. W. Manganese (III) Catalyzed Free Radical Reactions on Trimetallic Nitride Endohedral Metallofullerenes, J. Am. Chem. Soc. 2007, 127, 15710-15717.

270. Jain, V.; Yochum, H.; Wang, H.; Montazami, R.; Vidales-Hurtado, M. A.; Mendoza-Galván,A.; Gibson, H. W.; Heflin, J. R. Solid-State Electrochromic Devices via Ionic Self-Assembled Multilayers (ISAM) of a Polyviologen, Macromol. Chem. Phys. 2008, 209, 150-157.

271. Shu,C.-Y.; Ma, X.-Y.; Zhang, J.-F.; Corwin, F. D.; Dorn, H. C.; Gibson,H. W.; Zhang, E.-Y.; Chen, N.; Fillmore, H.; Fatouros,P. P.; Wang, C.-R.; Fang, X.-H.  Direct Conjugation of Water-soluble Gadolinium-Containing Endohedral Fullerides to Antibodies: A Model of Magnetic Contrast Agent with Tumor-targeting Potential, Bioconj. Chem. 2008, 19, 651-655.

272. Shu, C.; Wang, C.-R.; Zhang, J.-F.; Gibson, H. W.; Dorn, H. C.; Corwin, F. D.; Fatouros, P. P.; Dennis, T. J. S. Organophosphonate Functionalized Gd@C82 as a Magnetic Resonance Imaging Contrast Agent, Chem. Mater. 2008, 20, 2106-2109.

273. Cai, T.; Xu, L.; Shu, C.; Reid, J. E.; Champion, H. A.; Anklin, C.; Anderson, M. R.; Gibson, H. W.; Dorn, H. C. Formation of a Symmetric Sc3N@C78 Bisadduct: Multi-Adduct Docking Controlled by an Internal Trimetallic Nitride Cluster, J. Am. Chem. Soc.2008, 130, 2136-2137.

274. Pederson,A. M.-P.; Vetor, R. C.; Rouser,M. A.; Huang, F.; Slebodnick, C.; Schoonover, D. V.; Gibson, H. W. A New Functional Bis(meta-Phenylene)-32-Crown-10-Based Cryptand Host For Paraquats, J. Org. Chem. 2008, 73, 5570-5573.

275. Angeli, C. D.; Cai, T.; Duchamp, J. C.; Reid, J. E.; Singer, E. S.; Gibson, H. W.; Dorn, H. C. Purification of Trimetallic Nitride Templated Endohedral Metallofullerenes by a Chemical Reaction of Congeners with Eutectic 9-Methylanthracene, Chem. Mater. 2008, 20, 4993-4997.

276. Davis, R.; Garg, A.; Durak, C.; Gibson, H.; Heflin, R. Polar Orientation of a Pendant Anionic Chromophore in Thick Ionic Self-Assembled Multilayer Polymeric Films, J. Appl. Phys. 2008, 104, 053116.

277. Garg, A.; Heflin, R.; Gibson, H.; Davis, R. A Study of Film Structure And Adsorption Kinetics of Polyelectrolyte Multilayer Films: Effect of pH And Polymer Concentration, Langmuir 2008, 24, 10887-10894.

278. Pederson, A. M.-P.; Ward, E.; Schoonover, D. S.; Slebodnick, C.; Gibson, H. W. High-Yielding, Regioselective Synthesis of cis-Dicarbomethoxy-Dibenzo-30-crown-10, Its Conversion to a Pyridyl Cryptand and Strong Complexation of Bipyridinium Derivatives, J. Org. Chem. 2008, 73, 9094-9101.

279. Cai, T.; Xu, L.; Shu, C.; Reid, J. E.; Gibson, H. W.; Dorn, H. C. Synthesis and Characterization of a Non-IPR Fullerene Derivative: Sc3N@C68[C(COOC2H5)2], J. Phys. Chem. C 2008, 112, 19203-19208.

280. Shu, C.; Xu, L.; Cai, T.; Champion, H.; Reid, J. E.; Fu, W.; Zuo, T.; Dorn, H. C.; Gibson, H. W. Photochemical Derivatization of Trimetallic Nitride Templated Endohedral Metallofullerenes,J. Am. Chem. Soc. 2008, 130, 17755-17760.

REVIEWS, BOOKS, BOOK CHAPTERS

20. Huang, F.; Gibson, H. W. Polypseudorotaxanes and Polyrotaxanes, Progr. Polym. Sci., 2005, 30, 982-1018.

21. Huang, F.; Pederson, A. M.; Gibson, H. W. Polyrotaxanes, in Physical Properties of Polymers Handbook; Mark, J. E., ed.; Springer-Verlag: New York, 2007, 693-698. (Invited)

22. Pederson, A. M.-P.; Gibson, H. W. Multiple Macroheterocyclic Rings, chapter in Comprehensive Heterocyclic Chemistry III, Katritsky, A. R.; Taylor, R.; Ramsden, C.; Scriven, E., eds.-in-chief, Newkome, G. R., vol. ed., Elsevier, Oxford, UK, 2008; Vol. 14, pp. 1071 - 1086. (Invited)

PREPRINTS, UNREFEREED PUBLICATIONS

88. Heflin, J.; Neyman, P. J.; Durak, C.; Brands, C.; Guzy, M. T.; Gaskins, K.; Davis, R. M.; Gibson, H. W.; Van Cott, K. E.  Self-Assembled Organic Thin Films for Second Order Nonlinear Optics, Polym. Mater. Sci. Eng. (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2004, 91, 350.

89. Ganguly, S. C.; Gibson, H. W.  Synthesis of a Macrocyclic Biarylene Ether Sulfone Using Ni(0) Catalyst, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2005, 46(1), 98-99.

90. Ganguly, S. C.; Gibson, H. W.  One Step Synthetic Route to Macrocyclic Arylene Ether Sulfone and an Overview of the Future Applications of Macrocycle Within a Polymer, PMSE Preprints 200694,  232-233.

91. Durak, C.; Garg, A.; Chen, K.; Van Cott, K. E.; Davis, R. M.; Gibson, H. W.; Robinson, H. D.; Heflin, J. R.  Self Assembled Organic Thin Films for Second Order Nonlinear Optics, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.)  2006, 47(1), 1041-1042. 

92. Lee, M.; Schoonover, D.; Gibson, H. W. Synthesis of New Host and Guest Polymers and Their Self-Assembling Behavior, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.)  2008, 49(1), 107-108.

93. Gibson,H. W.; Huang, F.; Ge, Z.; Wang, H.; Pederson, A. M.-P.; Lee, M.; Rouser, M.; Schoonover, D. Mechanical Linkages (Pseudorotaxane Structures) in Self-Assembly and Modification of Macromolecules, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.)  2008, 49(1), 1030-1031.

94. Koppolu, V. R.; Gupta, M. C.; Bagienski, W.; Shen, Y.; Shu, C.; Gibson, H. W.; Dorn, H. C. A Novel Solution Processable Electron Acceptor, C60(CN)2, for Bulk Heterojunction Photovoltaic Applications, MRS Symp. Proc. 2009, submitted.

PATENTS

34. K. Van Cott, J. R. Heflin, Jr., H. W. Gibson, R. M. Davis, Polar Ordering of Reactive Chromophores in Layer-by-Layer Nonlinear Optical Materials, U. S. Patent 6,953,607 (2005).

35. K. Van Cott, J. R. Heflin, H. Gibson, R. M. Davis, Polar Ordering of Reactive Chromophores in Layer-By-Layer Nonlinear Optical Materials, U S Patent 7,258,924 (2007).

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1999-2003

REFEREED PUBLICATIONS

200. Gibson, H. W.; Engen, P. T. and Lee, S.-H. Synthesis of Poly[(styrene)-rotaxa-(crown ether)]s via Free Radical Polymerization,  Polymer 1999, 40, 1823-1832.

201. Gibson, H. W.; Dotson, D. L.; Marand, H. Swager, T. M. Synthesis and Characterization of Liquid Crystalline Triaryloxy-s-triazines, Mol. Cryst. Liq. Cryst. 1999, 326, 113-138.

202. Yamaguchi, N.; Gibson, H. W. Formation of Supramolecular Polymers from Homoditopic Molecules Containing Ammonium Ions and Crown Ethers, Angew. Chem. 1999, 111, 195-199; Angew. Chem. Int. Ed. 1999, 38, 143-147.

203. Mason, P. E.; Bryant, W. S.; Gibson, H. W. Threading/Dethreading Exchange Rates as Structural Probes in Polypseudorotaxanes, Macromolecules 1999, 32, 1559-1569.

204. Nagapudi, K.; Leisen, J.; Beckham, H. W.; Gibson, H. W. Solid State NMR Investigations of Poly[(acrylonitrile)-rotaxa-(60-crown-20), Macromolecules 1999, 32,3025-3033.

205. Yamaguchi, N.; Gibson, H. W. Stabilities of Cooperatively Formed Pseudorotaxane Dimers, J. Chem. Soc., Chem. Comm. 1999, 789-790.

206. Bryant, W. S.; Guzei, I.; Rheingold, A. L.; Gibson, H. W. Unique 'Cradled Barbell' Complex Between a Secondary Diammonium Ion and Bis-m-phenylene-32-crown-10, Org. Lett.1999,1,47-50.

207.Bryant, W. S.; Jones, J. W.; Mason,P. E.; Guzei,I.; Rheingold, A. L.; Fronczek, F. R.; Nagvekar,D. S.; Gibson, H. W.   A New Cryptand: Synthesis & Complexation with Paraquat, Org. Lett. 1999, 1, 1001-1004.

208. Yang, J.; Gibson, H. W. A Polyketone Synthesis Involving Nucleophilic Substitution via Carbanions Derived from Bis(a-aminonitrile)s.  5.  A New, Well Controlled Route to 'Long' Bisphenol and Activated Aromatic Dihalide Monomers, Macromolecules 1999, 32, 8740-8746.

209. Yang, J.; Tyberg, C. S.; Gibson, H. W.  A Polyketone Synthesis Involving Nucleophilic Substitution via Carbanions Derived from Bis(a-aminonitriles. 4. Aromatic Poly(ether ketone)s, Macromolecules 1999, 32, 8259-8268.

210.Bryant, W. S.; Jones, J. W.; Mason, P. E.; Guzei, I.; Rheingold, A. L.; Fronczek, F. R.; Nagvekar, D. S.; Gibson, H. W. A New Cryptand: Synthesis and Complexation with Paraquat (Correction), Org. Lett. 2000, 2, 417-417.  

211. Yamaguchi, N.; Gibson, H. W.  Non-covalent Chemical Modification of Crown Ether Side Chain Polymethacrylates with a Secondary Ammonium Salt: A New Polypseudorotaxane, Macromol. Chem. Phys. 2000, 201, 815-824.

212. Gibson, H. W.; Lee, S.-H. 42-Crown-14-Based [2]Catenane, Can. J. Chem. 2000, 78,347-355.

213. Gibson, H. W. Book Review: "Advances in Dendritic Macromolecules”, vol. 4, Newkome, G. R. JAI Press, Inc.  1999.  J. Am. Chem. Soc. 2000, 122, 5903.

214. Gibson, H. W.; Hamilton, L.; Yamaguchi, N. Molecular Self-Assembly of Dendrimers, Non-Covalent Polymers and Polypseudorotaxanes, Polym. Adv. Tech. 2000, 11, 791-797.

215. Piok, T.; Brands, C.; Neyman, P. J.; A. Erlacher, A.; Soman, C.; Murray, M. A.; Schroeder, R.; Graupner, W.; Heflin, J. R.; Marciu, D.; Drake, A.; Miller, M. B.; Wang, H.; Gibson, H.; Dorn, H. C.; Leising, G.; Guzy, M.; Davis, R. M. Photovoltaic Cells Based on Ionically Self-Assembled Nanostructures, Synthetic Metals 2001, 116, 343-347.

216. Gibson, H. W.; Bryant, W. S.; Lee, S.-H. Polyrotaxanes by Free Radical Polymerization of (Meth)acrylate Monomers in the Presence of Crown Ethers, J. Polym. Sci., Polym. Chem. Ed. 2001, 39, 1978-1993.

217. Gibson, H. W. Book Review: "Monographs in Supramolecular Chemistry: Self-Assembly in Supramolecular Systems", Lindoy, L. F.; Atkinson, I. M. Royal Society of Chemistry,J. Nat. Prod.  2001, 64, 691.

218. Schroeder, R.; Heflin, J. R.; Wang, H.; Gibson, H.; Graupner, W. Control of Excited State Dynamics in Ionically Self-Assembled Monolayers of Conjugated Molecules, Synthetic Metals 2001, 121, 1521-1524.

219. Gibson, H. W.; Yamaguchi, N. Hamilton, L. M.; Jones, J. W. "Cooperative Self-Assembly Of Dendrimers Via Pseudorotaxane Formation From A Homotritopic Guest Molecule And Complementary Monotopic Host Dendrons", J. Am. Chem. Soc. 2002, 124, 4653-4665.

220. Guzy, M. T.; Neyman, P. J.; Brands, C.; Heflin, J. R.; Gibson, H. W.; Davis, R. M.; Van Cott, K. E. Layer-by-Layer Deposition and Ordering of Low Molecular Weight Dye Molecules for Second Order Nonlinear Optics, Angew. Chem. Int. Ed. 2002, 41, 3236-3238.

221. Gibson, H. W. Book Review. “Advances in Dendritic Macromolecules”, vol. 5, Newkome, G. R. JAI Press, Inc.  2002. J. Am. Chem. Soc. 2002, 124, 13639.

222. Jones, J. W.; Zakharov, L. N.; Rheingold, A. L.; Gibson, H. W. Cooperative Host/Guest Interactions via Counterion Assisted Chelation: Pseudorotaxanes from Supramolecular Cryptands, J. Am. Chem. Soc. 2002, 124, 13378-13379.

223. Jones, J. W.; Bryant, W. S.; Bosman, A. W.; Janssen, R. A. J.; Meijer, E. W.; Gibson, H. W. Crowned Dendrimers: pH Responsive Pseudorotaxane Formation, J. Org. Chem. 2003,68, 2385-2389.

224. Gibson, H. W.; Yamaguchi, N.; Jones, J. W. Supramolecular Pseudorotaxane Polymers from Complementary Pairs of Homoditopic Molecules, J. Am. Chem. Soc. 2003, 125, 3522-3533.

225. Van Cott, K. E.; Amos, T.; Gibson, H.; Davis, R. M.; Heflin, J. R. Purity and Stability of Commercially Available Dichlorotriazine Chromophores Used in Nonlinear Optical Materials, Dyes & Pigments2003, 58, 145-155.

226. Zhao, T; Beckham, H. W.; Gibson, H. W. Quantitative Determination of Threading in Rotaxanated Polymers by Diffusion-Ordered NMR Spectroscopy, Macromolecules 2003, 36, 4833 - 4837.

227. Huang, F.; Fronczek, F. R. Gibson, H. W. First Supramolecular Poly(taco complex), J. Chem. Soc., Chem. Commun. 2003, 1480 - 1481.

228. Jones, J. W.; Gibson, H. W. Ion Pairing and Host-Guest Complexation in Low Dielectric Constant Solvents, J. Am. Chem. Soc. 2003, 125, 7001-7004.

229. Huang, F.; Fronczek, F. R.; Gibson, H. W. A Cryptand-based [3]Pseudorotaxane: Cooperative Complexation between A Cryptand and A Bisparaquat Guest, J. Am. Chem. Soc. 2003, 125, 9272 - 9273.

230. Huang, F.; Gibson, H. W.; Bryant, W. S.; Nagvekar, D. S.; Fronczek, F. R. First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures, J. Am. Chem. Soc. 2003, 125, 9367-9371.

231. Huang, F.; Zhakarov, L.; Rheingold, A. L.; Jones, J. W.; Gibson, H. W. Water Assisted Formation of a Pseudorotaxane and Its Dimer Based on a Supramolecular Cryptand, J. Chem. Soc., Chem. Commun. 2003, 2122-2123.

232. Huang, F.; Jones, J. W.; Gibson, H. W. Ion Pairing in Fast-Exchange Host-Guest Systems: Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions, J. Am. Chem. Soc. 2003, 125, 14458-14464.

REVIEWS, BOOKS, BOOK CHAPTERS

18. Gong, C.; Gibson, H. W. Polyrotaxanes: Syntheses and Properties, in Molecular Catenanes, Rotaxanes and Knots, Sauvage, J.-P.; Dietrich-Buchecker, C. O., eds., Wiley-VCH, Weinheim, 1999, ch. 11, pp. 277-321. (Invited)

19. Mahan, E.; Gibson, H. W., "Rotaxanes", in Cyclic Polymers, 2nd ed., Semlyen, A. J., ed., Kluwer Publishers, Dordrecht, 2000, ch. 12, pp. 415-560. (Invited)

PREPRINTS, UNREFEREED PUBLICATIONS

59. Yamaguchi, N.; Gibson, H. W. Noncovalent Polymers, Polym. Mater. Sci. Eng. (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 1999, 80, 217-218.

60. Brands, C.; Piok, T.; Erlacher, A.; Neyman, P. J.; Marciu, D.; Miller, M. B.; Wang, H.; Gibson, H. W.; Dorn, H. C.; Davis, R. M.; Graupner, W.; Heflin, J. R. Photovoltaic Responses in Ionically Self-Assembled Polymer-Fullerene Nanostructures, SPIE Proc. 1999, 3937, 51-62.

61. Gibson, H. W.; Yamaguchi, N. Side Chain Poly(methacrylate pseudorotaxane)s, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2000, 41(1), 18-19.

62. Neyman, P. J.; Guzy, M. T.; Shah, S.; Wang, H.; Gibson, H. W.; Van Cott, K. E.; Davis, R. M.; Figura, C.; Heflin, J. R. Second Order Nonlinear Optical Properties of Ionically Self-Assembled Films Containing Dianionic Chromophores, Polym. Mater. Sci. Eng.  (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2000, 83, 162-163.

63. Brands, C.; Neyman, P. J.; Guzy, M. T.; Shah, S.; Wang, H.; Gibson, H. W.; Van Cott, K. E.; Davis, R. M.; Figura, C.; Heflin, J. R. In Situ Second Harmonic Generation Measurements of the Growth of Nonlinear Optical Ionically Self-Assembled Monolayers,Polym. Mater. Sci. Eng.  (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2000, 83, 219-220.

64. Guzy, M. T.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Heflin, J. R.; Wang, H.; Gibson, H. W. Novel Deposition Techniques for Self-Assembled Non-Linear Optic Thin Films,Polym. Mater. Sci. Eng.  (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2000, 83, 260.

65. Graupner, W.; Piok, T.; Brands, C.; Neyman, P. J.; Erlacher, A.; Soman, C.; Murray, M. A.; Schroeder, R.; Heflin, J. R.; Marciu, D.; Drake, A.; Miller, M. B.; Wang, H.; Gibson, H.; Dorn, H. C.; Leising, G.; Guzy, M.; Davis, R.M. Efficient Charge Generation in Conjugated Molecules, Polym. Mater. Sci. Eng.  (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2000, 83, 284-285.

66. Marciu, D.; Miller, M. B.; Heflin, J. R.; Murray, M. A.; Neyman, P. J.; Graupner, W.; Wang, H.; Gibson, H. W.; Davis, R. M. Characterization of Polymer Light-Emitting Diodes Fabricated by Ionically Self-Assembled Monolayer Technique, Mater. Res. Soc. Symp. Proc. 2000, 598, BB11.50.1-6.

67. Marciu, M. B.; Miller, M.; Ritter, A. L.; Murray, M. A.; Neyman, P. J.; Graupner, W.; Heflin, J. R.; Wang, H.; Gibson, H. W.; Davis, R.M. Efficiency Optimization in Ionically Self-Assembled Thin Film Polymer Light-Emitting Diodes, Proc. SPIE 2000, 3938, 169-179.

68. Brands, C.; Piok, T.; Neyman, P. J.; Erlacher, A.; Soman, C.; Murray, M. A.; Schroeder, R.; Heflin, J. R.; Graupner, W.; Marciu, D.; Drake, A.; Miller, M. B.; Wang, H.; Gibson, H.; Dorn, H. C.; Leising, G.; Guzy, M.; Davis, R. M.  Photovoltaic Responses in Ionically Self-Assembled Nanostructures Containing Conjugated Polymers and Fullerenes, Proc. SPIE 2000, 3937, 51-62.

69. Gibson, H. W.; Bosman, A. W.; Bryant, W. S.; Jones, J. W.; Janssen, R. A. J.; Meijer, E. W. Cooperative Complexation of Dendritic Hosts, Polym. Mater. Sci. Eng. (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2001, 84, 66-67.

70. Gibson, H. W.; Guzy, M. T.; Shah, S.; Wang, H.; Neyman, P. J.; Van Cott, K. E.; Davis, R. M.; Brands, C.; Figura, C.; Heflin, J. R.; Second Order Nonlinear Optical Properties of Ionically Self-Assembled Films,Polym. Mater. Sci. Eng.  (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 2001, 84, 251-252.

71. Schroeder, R.; Soman, C.; Brands, C.; Heflin, J. R.; Graupner, W.; Wang, H.; Gibson, H.; Marciu, D.; Miller, M. B. Photoluminescence Studies On Energy Migration in Multilayer Organic Photovoltaic Devices based on Ionically Self-Assembled  Monolayers,  SPIE Proc. 2001, 4108, 85-96.

72. Janik, J. A.; Heflin, J. R.; Marciu, D.; Miller, M. B.; Wang, H.; Gibson, H. W.; Davis, R. M.  Electrochromic Switching in Ionically Self-Assembled Nanostructures. SPIE Proc. 2001, 4458, 146-153.

73. Neyman, P. J.; Guzy, M. T.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H. W.; Brands, C.; Heflin, J. R. Second Order Nonlinear Optical Responses of Ionically Self-Assembled Films: Polycation Variations and Dianionic Chromophores, SPIE Proc. 2001, 4461, 214-225.

74. Brands, C.; Neyman, P. J.; Guzy, M. T.; Shah, S.; Van Cott, K. E.; Davis, R. M.; Wang, H.; Gibson, H. W.; Heflin, J. R.  In Situ Second Harmonic Generation Measurements of the Growth of Nonlinear Optical Ionically Self-Assembled Monolayers, MRS Symp. Proc. 2001, 660, JJ8.30, 1-6.

75. Brands, C.; Neyman, P. J.; Guzy, M. T.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H.W.; Heflin, J. R. In Situ Second Harmonic Generation Measurements of the Formation of Ionically Self-Assembled Monolayers, SPIE Proc. 2001, 4461, 311-318.

76. Neyman, P. J.; Guzy, M. T.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H. W.; Brands, C.; Heflin, J. R. Novel Hybrid Covalent / Ionic Self-Assembly Technique for Improved Second-Order Nonlinear Optical Films, MRS Symp. Proc. 2002, 708;BB4.4, 2002, 708;BB4.4, 161-166.

77. Marciu, D.; Miller, M. B.; Kozikowski, C.; Heflin, J. R.; Cho, S.; Reid, B. A.; Kuroda, K.; Graupner, W.; Wang, H.; Gibson, H. W.; Davis, R. M. Enhanced Photovoltaic Response in Ionically Self-Assembled Monolayer Thin-Film Devices, MRS Symp. Proc. 2002, 708;BB9.4, 277-283.

78. Brands, C.; Neyman, P. J.; Guzy, M. T.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H. W.; Heflin, J. R. In Situ Measurements of the Formation of Ionically Self-Assembled Monolayers by Second Harmonic Generation, MRS Symp. Proc. 2002, 707, 313-318.

79. Neyman, P. J.; Guzy, M.; Shah, S.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H. W.; Brands, C.; Heflin, J. R. Novel Hybrid Covalent/Ionic Self-Assembly Technique for Improved Second-Order Nonlinear Optical Films, Polymer Preprints(Am. Chem. Soc., Div. Polym. Chem.) 2002, 43(2), 560-561.

80. Heflin, J. R.; Janik, J.; Marciu, D.; Miller, M.; Wang, H.; Gibson, H. W.; Davis, R. M.; Electrochromic Devices Fabricated from Ionically Self-Assembled Thin Films of Conjugated Polymers and Polymer Electrolytes, Polymer Preprints(Am. Chem. Soc., Div. Polym. Chem.) 2002, 43(2), 510-511.

81. Wang, H.; Chng, C. P.; Gibson, H. W.; Rheingold, A. L. Synthesis and Polymerization of a Novel Crown Ether: Bis(5-carboxy-1,3-phenylene)-14-crown-4, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2002, 43(2), 1077-1078.

82. Heflin, J. R.; Neyman, P. J.; Guzy, M.; Shah, S. M.; Davis, R. M.; Van Cott, K. E.; Wang, H.; Gibson, H. W.; Brands C. Hybrid Covalent/Ionic Self-Assembly of Organic Second Order Nonlinear Optical Films, in Organic Thin Films for Photonic Applications, OSA Trends in Optics and Photonics Series 2002, 64, 3-8.

83. Marciu, D.; Miller, M. B.; Kozikowski, C.; Heflin, J. R.; Cho, S.; Reid, B. A.; Kuroda, K.; Graupner, W.; Wang, H.; Gibson, H. W.; Davis, R. M. Photovoltaic Response in Conducting Polymer/Fullerene Self-Assembled Multilayers, in Organic Thin Films for Photonic Applications, OSA Trends in Optics and Photonics Series 2002, 64, 103-109.

84. Brands, C.; Neyman, P. J.; Guzy, M. T.; Shah, S.; Van Cott, K. E.; Davis, R. M.; Wang, H.; Gibson, H. W.; Heflin, J. R.  In Situ Measurement of the Second Harmonic Signal of Adsorbing Nonlinear Optical Ionically Self-Assembled Monolayers, MRS Symp. Proc. 2002, 710, 201-206.

85. Ge, Z.; Jones, J. W.; Gibson, H. W. Non-Covalent Block Copolymers By Self-Assembly: New Polypseudorotaxanes. Polymer Preprints(Am. Chem. Soc., Div. Polym. Chem.) 2002, 43(1), 611-612.

86. Gibson, H. W.; Ge, Z.; Jones, J. W.; Farcas, A. Self-Assembly with Macromolecular Building Blocks, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2003, 44(1), 608-609.

87. Gibson, H. W.; Ge, Z.; Huang, F.; Jones, J. W.; Wang, H.; Farcas, A. Mechanically Interlocked Macromolecular Systems Via Pseudorotaxane Self-Assembly, Polymer Preprints (Am. Chem. Soc., Div. Polym. Chem.) 2003, 44(2), 475-476.

PATENTS

33. C. Gong and H. W. Gibson, Reversible, Mechanically Interlocked Polymeric Networks Which Self-Assemble, U. S. Patent 6,100,329 (2000).

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1994-1998

REFEREED PUBLICATIONS

148. Gibson, H. W.; Delaviz, Y. Bis(5-carbomethoxy-1,3-phenylene)-30-crown-4:  A Macrocyclic Monomer of Predominantly Hydrocarbon Character, Polymer1994, 34, 1109-1110.

149. Leblanc, J. P.; Rorrer, K.; Gibson, H. W. Synthesis of Star Shaped Dispersant Based on Reissert Chemistry, J. Org. Chem.1994, 59, 674-675.

150. Leblanc, J. P.; Gibson, H. W. One Pot Synthesis and Utility of Open Chain Reissert Compounds in Synthesis of Unsymmetrical Imides, a-Aminocarboxamides, Imidazalones and Hydantoins J. Org. Chem.1994, 59, 1072-1077.

151. Shen, Y. X.; Xie, D.; Gibson, H. W. Polyurethane-Crown Ether Based Polyrotaxanes. Part I: Synthesis, J. Am. Chem. Soc.1994, 116, 537-548.

152 .Bheda, M.; Merola, J.; Woodward, W.; Vasudevan, V.; Gibson, H. W. Crystal Structures of 30-Crown-10 and Its Tetrahydrate, J. Org. Chem.1994, 59, 1694-1702.

153 .Pandya, A.; Yang, J.; Gibson, H. W. A New Polyketone Synthesis Involving Nucleophilic Substitution via Carbanions Derived from Bis(a-Aminonitrile)s I: Semicrystalline Poly(Arylene Ketone Sulfone)s, Macromolecules1994, 27, 1367-1375.

154. Gibson, H. W.; Bheda, M. C.; Engen, P.; Shen, Y. X.; Sze, J.; Zhang, H.; Gibson, M. D.; Delaviz, Y.; Lee, S. H.; Wang, L.; Rancourt, J.; Taylor, L. T. Synthesis and Characterization of Large (30-60 Membered) Aliphatic Crown Ethers, J. Org. Chem.1994, 59, 2186-2196.

155. Jois, Y.; Gibson, H. W. Attempted Polymerization of Benzimidazole via Reissert Reactions, Macromolecules1994, 27, 2912-2916.

156. Liu, S.; Gibson, H. W. Difunctional Blocking Groups for Rotaxanes and Polyrotaxanes, Tetrahedron Lett.1994, 35, 8533-8536.

157. Loveday, D.; Wilkes, G. L.; Bheda, M. C.; Shen, Y. X.; Gibson, H. W. Structure-Property Relationships in Segmented Polyviologen Ionene Rotaxanes, J. Macromol. Sci., A-Chem.1995, A32, 1-27.

158. Gibson, H. W.; Liu, S.; Lecavalier, P.; Wu, C.; Shen, Y. X. Synthesis and Preliminary Characterization of Some Polyester Rotaxanes, J. Am. Chem. Soc. 1995, 117, 852-874.

159. Delaviz, Y.; Merola, J. S.; Berg, M. A. G.; Gibson, H. W. Syntheses, X-Ray Structures, Complexation and Thermal Stability Studies of Bis(5-carbomethoxy-1,3-phenylene)-(3x+2)-crown-x Compounds, J. Org. Chem.1995, 60, 516-522.

160. Gibson, H. W.; Bheda, M. C. Synthesis and Polymerization of a Bulky Styrenic Monomer as an In-Chain Knot for Polyrotaxanes, Polymer1995, 36, 2615-2619.

161 .Liu, S.; Lee, S.-H.; Gibson, H. W. Knots for Molecular Strings of Beads, J. Org. Chem.1995, 60, 3155-3162.

162. Gibson, H. W.; Liu, S.; Lee, S.-H.; Marand, H.; Prasad, A.; Wang, F.; Bheda, M.; and Nagvekar, D. More Fun and Games with Rings, Strings and Rods, Makromol. Chem., Macromol. Symp. 1995, 98, 501.

163. Nagvekar, D.; Delaviz, Y.; Prasad, A.; Merola, J. S.; Srinivasan, S.; Marand, H.; Gibson, H. W. Synthesis and Properties of Cholesteryl Esters Bearing 32- and 16-Membered Crown Ethers, J. Org. Chem. 1996, 61, 1211-1218.

164. Gibson, H. W.; Liu, S. Polyrotaxanes: Past, Present and Future, Makromol. Chem., Macromol. Symp.1996, 102, 55-61.

165. Marand, E.; Hu, Q.; Gibson, H. W.; Veytsman, B. Spectroscopic Characterization of Hydrogen Bonding in Poly(urethane rotaxane)s, Macromolecules1996, 29, 2555-2562.

166. Xie, D.; Gibson, H. W. A 40-Membered Macrocyclic Arylene Ether Disulfone from Bisphenol-A: Improved Synthesis and Properties, Macromol. Chem. Phys.1996, 197, 2133-2148.

167. Chen, M.; Gibson, H. W.  Large Sized Macrocyclic Monomeric Precursors of Poly(ether ether ketone): Synthesis and Polymerization, Macromolecules1996, 29, 5502-5504.

168. Gong, C.; Gibson, H. W. Synthesis and Characterization of a Polyester/Crown Ether Rotaxane Derived from a Difunctional Blocking Group,Macromolecules1996, 29, 7029-7033.

169. Chen, M.; Fronczek, F.; Gibson, H. W.  Concise Synthesis of 30-Membered Macrocyclic Monomer for Poly(ether ether ketone), Macromol. Chem. Phys.1996, 197, 4069-4078.

170. Lee, S.-H.; Engen, P. T.; Gibson, H. W. Blocking Group/Initiators for the Synthesis of Polyrotaxanes via Free Radical Polymerizations,  Macromolecules 1997, 30, 337-343.

171. Nagvekar, D. S.; Gibson, H. W. An Improved Synthesis for Bis(p-phenylene)-32-crown-4, Org. Prep. Proced. Int.1997, 29, 234-236.

172. Nagvekar, D.; Gibson, H.W. Improved Syntheses of 20- and 26-Membered Bis(5-carbomethoxy-1,3-phenylene) Crown Ethers,  Org. Prep. Proced. Intern.1997, 29, 237-240.

173. Nagvekar, D. S.; Gibson, H. W. 5-Benzyloxyresorcinol: A Monoprotected Phloroglucinol Org. Prep. Proced. Int.1997, 29, 240-242.

174. Chen, M.; Guzei, I.; Rheingold, A. L.; Gibson, H. W. Novel Macrocycle by Friedel-Crafts Acylation Cyclization, Macromolecules1997, 30, 2516-2518.

175. Gong, C.; Gibson, H. W. A Self-threading-based Approach for Branched and/or Crosslinked Poly(methacrylate rotaxane)s, J. Am. Chem. Soc.1997, 119, 5862-5866.

176. Gibson, H. W.; Liu, S.; Gong, C.; Joseph, E. Studies of the Formation of Poly(ester rotaxane)s  from Diacid Chlorides, Diols and Crown Ethers and Their Properties, Macromolecules1997, 30, 3711-3727.

177. Gong, C; Gibson, H. W. Dethreading During the Preparation of Polyrotaxanes, Macromol.  Chem. Phys. 1997, 198, 2331-2342.

178. Gibson, H. W.; Nagvekar, D. S.; Yamaguchi, N; Wang, F.; Bryant, W. S. Syntheses of Monofunctional Derivatives of m-Phenylene-16-crown-5, Bis(m-phenylene)-32-crown-10 and m-Phenylene-p-phenylene-33-crown-10,  J. Org. Chem.1997, 62, 4798-4803.

179. Gong, C.; Ji, Q.; Glass, T. E.; Gibson, H. W. A Stategy to Eliminate Dethreading During the Preparation of Poly(ester/crown ether rotaxane)s: Use of Difunctional Blocking Groups, Macromolecules1997, 30, 4807-4813.

180. Xie, D.; Ji, Q.; Gibson, H. W. Synthesis and Ring Opening Polymerization of Single Sized Aromatic Macrocycles for Poly(arylene ether)s, Macromolecules1997, 30, 4814-4827.

181. Lee, S.-H.; Gibson, H. W. Hydrocarbon-Based 40- and 44-Membered Macrocycles as Components of Polyrotaxanes, Macromolecules1997, 30, 5557-5559.

182. Yang, J.; Gibson, H. W.  A New Polyketone Synthesis Involving Nucleophilic Substitution via Carbanions Derived from Bis(a-aminonitrile)s. 2. Wholly Aromatic Polyketones Without Ether Linkages, Macromolecules1997, 30, 5629-5633.

183. Gong, C.; Gibson, H. W. Controlling Topology by Polymerization Conditions: Physically Branched and Network Poly(urethane rotaxane)s with Controllable Polydispersity, J. Am. Chem. Soc. 1997, 119, 8585-8591.

184. Gibson, H. W.; Nagvekar, D. S.; Xie, D. Difunctional 28-Membered Cyclic Arylene Ethers, J. Org. Chem. 1997, 62, 7503-7506.

185. Gibson, H. W.; Nagvekar, D.; Powell, J.; Gong, C.; Bryant, W. Polyrotaxanes by In Situ Self Threading During Polymerization of Functional Macrocycles. Part 2. Poly(ester crown ether)s, Tetrahedron1997, 53, 15197-15207.

186. Gong, C.; Gibson, H. W. Controlling Microstructure in Polymeric Molecular Shuttles: Solvent-Induced Localization of Macrocycles in Poly(urethane crown ether rotaxane)s, Angew. Chem. 1997, 109, 2426-2428; Angew. Chem. Int. Ed. Engl. 1997, 36, 2331-2333.

187. Gibson, H. W.; Nagvekar, D. S. Syntheses of Some Difunctional Bis(m-phenylene)-32-crown-10 Derivatives, Can. J. Chem.1997, 75, 1375-1384.

188. Gong, C.; Gibson, H. W. A Method for Comparison of Threading Efficiencies of Different Macrocycles: A Competitive Trapping Methodology Based on Hybrid Polyrotaxanes, Macromolecules1997, 30, 8524-8525.

189. Gong, C.; Gibson, H. W. Poly(urethane/crown ether rotaxane)s with Solvent Switchable Microstructures, Macromolecules1998, 31, 308-313.

190. Gong, C.; Subramanian, C.; Ji Q.; Gibson, H. W. Main Chain Polyrotaxanes by Threading a Crown Ether Onto a Preformed Polyurethane: Preparation and Properties, Macromolecules1998,31, 1814-1818.

191. Gong, C.; Gibson, H. W. Self Assembly of Novel Polyrotaxanes: Part I. Main Chain Polypseudorotaxanes with Poly(ester crown ether) Backbones, Angew. Chem. 1998, 110, 323-327; Angew. Chem. Int. Ed. Engl. 1998, 37, 310-314.

192. Gibson, H. W.; Gong, C.; Liu, S.; Nagvekar, D. New Polymer Architectures: Recent Results With Polyrotaxanes, Macromol. Symp. 1998, 128, 89-98.

193. Gong, C.; Balanda, P. B.; Gibson, H. W. Supramolecular Chemistry with Macromolecules: New Self Assembly-Based Main Chain Polyrotaxanes and Their Properties, Macromolecules 1998, 31, 5278-5289.

194. Gibson, H. W.; Dotson, D. L. Wholly Aromatic Polymeric Ketones from Bis(a-aminonitrile)s via Soluble Poly(bisaminonitrile)s, Polymer 1998, 39, 6483-6487.

195. Yamaguchi, N.; Nagvekar, D. and Gibson, H. W. Self Organization of a Heteroditopic Molecule to Linear Polymolecular Arrays in Solution, Angew. Chem. 1998, 110, 2518-2520;Angew. Chem. Int. Ed. Engl. 1998, 38, 2361-2364.

196. Gong, C.; Gibson, H. W. Supramolecular Chemistry with Macromolecules: Macromolecular Knitting, Reversible Formation of Branched Polyrotaxanes by Self-Assembly, Macromol.  Chem. Phys. 1998, 199, 1801-1806.

197. Bryant, W. S.; Guzei, I. A.; Rheingold, A. L.; Gibson, H. W. Self Assembly of meta-Phenylene Crown Ethers and Secondary Ammonium Salts to Form Pseudorotaxanes, J. Org.  Chem. 1998, 63,7634-7639.

198. Gibson, H. W.; Nagvekar, D.; Delaviz, Y.; Bryant, W. S. Synthesis of a New Class of Difunctional Tetraphenylene Crown Ethers, Can. J. Chem. 1998, 76, 1429-1436.

199. Yamaguchi, N.; Hamilton, L. M.; Gibson, H. W. Dendritic Pseudorotaxanes, Angew. Chem. 1998, 110, 3463-3466;Angew. Chem. Int. Ed. 1998, 37, 3275-3279.

REVIEWS, BOOKS, BOOK CHAPTERS

13. Gibson, H. W.; Bheda, M. C.; Engen, P. T. Rotaxanes, Catenanes, Polyrotaxanes, Polycatenanes and Related Materials, Prog. Polym. Sci., 1994, 19, 843-945. (Invited)

14. Gibson, H. W.; Liu, S.; Shen, Y. X.; Bheda, M. C.; Lee., S.-H.; Wang, F. The Polyrotaxane Architecture. A New Approach to Molecular Engineering, NATO ASI Series, Kluwer Acad. Pub., Dordrect, the Netherlands, Series C, Vol. 456, 1995, pp. 41-58. (Invited)

15. Gibson, H. W.; Leblanc, J.-P. Reissert Polymers, The Polymeric Materials Encyclopedia: Synthesis, Properties and Applications, CRC Press Inc., 1996, pp. 7462-7467. (Invited)

16. Gibson, H. W. Rotaxanes, chapter in Large Ring Molecules, J. A. Semlyen, ed., J. Wiley and Sons, New York, 1996, ch. 6, pp. 191-262. (Invited)

17. Gong, C.; Gibson, H. W. Polyrotaxanes and Related Structures: Synthesis and Properties, Curr. Opin. Solid St. Mater. Sci., 1998, 2, 647-652. (Invited)

PREPRINTS, UNREFEREED PUBLICATIONS

51. Xie, D.; Gibson, H. W., Arylene Ether Macrocyclic Monomers for High Performance Polymers, Polymer Prepr. 1994, 35(1), 401.

52. Nagvekar, D.; Gibson, H. W., Synthesis of Poly(crown ether)s Based on Bis(5-carboxy-1,3-phenylene)-26-crown-8, Polymer Prepr. 1996, 37(2), 299.

53. Gibson, H. W.; Nagvekar, D.; Bhattacharjee, S. Polyrotaxanes by Self Threading of Functionalized Macrocycles: Polymethacrylates, Polymer Prepr. 1997, 38(1), 481.

54. Gibson, H. W.; Nagvekar, D.; Yamaguchi, N.; Bryant, W. S.; Bhattacharjee, S., Polyrotaxanes by Self Threading of Functionalized Macrocycles: Polyamides, Polymer Prepr. 1997, 38(1), 64.

55. Gibson, H. W.; Nagvekar, D.; Bryant, W. S.; Powell, J.; Bhattacharjee, S. Polyrotaxanes by Self Threading of Functionalized Macrocycles: Polyesters, Polymer Prepr. 1997, 38(1), 115.

56. Nagapudi, K.; Gibson, H. W.; Beckham, H. W., NMR Studies of Polyrotaxanes: Poly[(acrylonitrile)-rotaxa-(60-crown-20)], Polym. Mater. Sci. Eng. (Am. Chem. Soc. Div. Polym. Mater. Sci. Eng.) 1998, 79(1), 130-131.

PATENTS

28. H. W. Gibson and Y. Delaviz, Dibenzo Crown Monomers and Polymers Formed Therefrom, US Patent 5,302,729 (1994).

29. H. W. Gibson and Y. Delaviz, Mono- and Di(Functionally-Substituted Phenylene) Semi-Rigid Crowns and Precursors Thereof, U. S. Patent 5,331,098 (1994).

30. H. W. Gibson and A. Pandya, Commercially Valuable Polymeric Ketones and Method for Preparing Same, U. S. Patent 5,344,914 (1994).

31. Y. Delaviz, A. Gungor, J. E. McGrath and H. W. Gibson, Aramid Compositions of Improved Solubility and Flame Resistance, U. S. Patent 5,420,225 (1995).

32. H. W. Gibson and A. Pandya, Methods of Preparing Polymeric Ketones, U.S. Patent 5,442,029 (1995).

Foreign Patents

13. H. W. Gibson and Y. H. R. Jois, Bis(Reissert Compounds) From Reaction Of Monoaldehyde, Monoamine And Diacid Halide, European Patent 580744A1 (1994).

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1984-1993

REFEREED PUBLICATIONS

89. Gibson, H. W.  Conductive Polymers: An Opportunity for New Monomers and Polymers, in New Monomers and Polymers, B. M. Culbertson and C. U. Pittman, Eds., Plenum Pub. Co., New York, N.Y., 1984, 381-397. (Invited).

90. Feldblum, A.; Bigelow, R. W.; Gibson, H. W.; Epstein, A. J.; Tanner, D. B.  Nearly Metallic [CH(I3)y]x-Importance of Solitons, Crystal Order, Hopping and Band Conduction, Mol. Cryst. Liq. Cryst.1984, 105, 191-202.

91. Epstein, A. J.; Rommelmann, H.; Gibson, H. W.  Frequency Dependent Conductivity of Lightly Doped Cis-Polyacetylene:  Role of Multiply Connected Doped Trans-Polyacetylene Regions, Synthetic Metals 1984, 9, 103-114.

92. Epstein, A. J.; Bigelow, R. W.; Feldblum, A.; Gibson, H. W.; Hoffman, D. M.; Tanner, D. B.  Solitons, Disorder and Charge Conduction in Nearly Metallic Polyacetylene, Synthetic Metals 1984, 9, 155-164.

93. Pouget, J. P.; Robin, P.; Comes, R.; Gibson, H. W.; Epstein, A. J.; Billaud, D.  Structural Properties of a Conducting Polymer:  Doped (CH)x, Physica 1984, 127B, 158-164.

94. Sokol, P. E.; Gaines, J. R.; Cho, S. I.; Tanner, D. B.; Gibson, H. W.; Epstein, A. J.  Very Low Temperature Nuclear Spin Diffusion in Trans-Polyacetylene, Synthetic Metals 1984, 10, 43-49.

95. Gibson, H. W.; Weagley, R. J.; Mosher, R. A.; Kaplan, S.; Prest, W. M. Jr.; Epstein, A. J.  Molecular Structure of Trans-Polyacetylene: The Presence of Remnant Cis Units and Their Influence on Soliton Formation and Diffusion, Phys. Rev. B. 1985, 31, 2338-2342.

96. Epstein, A. J.; Rommelmann, H.; Gibson, H. W.  Frequency Dependent Conductivity of Cis-Polyacetylene, Phys. Rev. B 1985, 31, 2502-2505.

97. Pouget, J. P.; Pouxviel, J. C.; Robin, P.; Comes, R.; Begin, D.; Billaud, D.; Feldblum, A.; Gibson, H. W.; Epstein, A. J. Structural Study of Polyacetylene Doped with Tetrahedral Anions, Mol. Cryst. Liq. Cryst. 1985, 117, 75-82.

98. Epstein, A. J.; Bigelow, R. W.; Rommelmann, H.; Gibson, H. W.; Weagley, R. J.; Feldblum, A.; Tanner, D. B.; Pouget, J. P.; Pouxviel, J. C.; Comes, R.; Robin, P.  Density of States and Hopping Conductivity in Nearly Metallic Polyacetylene, Mol. Cryst. Liq. Cryst. 1985, 117, 147-154.

99. Yang, X. Q.; Tanner, D. B.; Feldblum, A.; Gibson, H. W.; Rice, M. J.; Epstein, A. J.  Optical Properties of Heavily Doped Polyacetylene, Mol Cryst. Liq. Cryst.1985, 117, 267-274.

100. Gibson, H. W.; Weagley, R. J.; Mosher, R. A.; Kaplan, S.; Prest, W. M. Jr.; Epstein, A. J.  Remmant Cis Bonds in Trans-Polyacetylene, Mol. Cryst. Liq. Cryst.1985, 117, 315-318.

101. Zemach, R.; Vardeny, Z.; Brafman, O.; Ehrenfreund, E.; Epstein, A. J.; Weagley, R. J.; Gibson, H. W.  Photoinduced Spectroscopy and Resonant Raman Study of Poly(1,6-heptadiyne), Mol. Cryst. Liq. Cryst.1985, 118, 423-426.

102. Gibson, H. W.; Weagley, R. J.; Mosher, R. A.; Kaplan, S.; Prest, W. M., Jr.; Epstein, A. J.  Chemical Evidence for Remnant Cis Bonds in Trans-Polyacetylene, Brit. Polym. J. 1986, 18, 115-119.

103. Gibson, H. W.; Weagley, R. J.  Approaches to Terminal Diacetylenes, Precursors to Substituted Polyacetylenes, Brit. Polym. J. 1986, 18, 120-126.

104. Weagley, R. J.; Gibson, H. W.  Dialkylation of Diesters, Synthesis 1986, 552-554. 

105. Gibson, H. W.; Kaplan, S.; Mosher, R. A.; Prest, W. M. Jr.; Weagley, R. J.  Isomerization of Polyacetylene Films of the Shirakawa Type - Spectroscopy and Kinetics, J. Am. Chem. Soc. 1986, 108, 6843-6851. 

106. Gibson, H. W.; Kurek, P. R. Synthesis and Properties of Poly(vinyl t-butyl carbonate), Polymer Comm.1987, 28, 97-99. 

107. Yang, X. Q.; Tanner, D. B.; Rice, M. J.; Gibson, H. W.; Flebdlum, A.; Epstein, A. J.  Transition to a Gapless Incommensurate Peierls Insulator in Heavily Doped Polyacetylene, Solid State Comm. 1987, 61, 335-340. 

108. Gibson, H. W. Novel Tricyclic Heterocycles (Benzopyrrocolines) Arising Via Carbanion Attack on a Nitrile Function, J. Heterocyclic Chem. 1989, 26, 361-364.

109. Guilani, B.; Rasco, M. L.; Hermann, C. F. K.; Gibson, H. W. 4,4'-Coupled Bis(isoquinolines), J. Heterocyclic Chem. 1990, 27, 1007-1009.

110. Gibson, H. W.; Guiliani, B. Regioselectivity in the Alkylation of 1-Acyl-1,2-dihydroquinaldonitriles (Quinoline Reissert Compounds), J. Org. Chem. 1990, 55, 4226-4229

111. Gibson, H. W.; Guilani, B. Polymers From Reissert Compounds. 3. Polyesters from Reactions of Dialdehydes with with Reissert Compounds From Bis(isoquinolines), Macromolecules 1990, 23, 4339-4340.

112. Jois, Y. H. R.; Gibson, H. W. Synthesis of 2-Cyano-1,3-dibenzoyl-2,3-dihydrobenzimidazole:  A New Novel Reissert Compound From Benzimidazole, J. Org. Chem. 1991, 56, 865-867.

113. Gibson, H. W.; Pandya, A.; Guilani, B.; Rasco, M. L.; Jois, Y. H. R. Synthesis of Difunctional Reissert Compounds Using Diacid Chlorides, Polymer Commun.1991, 32, 13-16.

114. Pandya, A.; Gibson, H. W. Polymers from Reissert Compounds.  7:  Novel Thermoplastic Polyamine Derivatives from Acyclic Reissert Compounds, Polymer Bull. 1991, 25, 17-24.

115. Delaviz, Y.; Gibson, H. W. One-Step Synthesis of Bis(meta-phenylene)-32-Crown-10, Polymer Commun. 1991, 32, 103-105.

116. Pandya, A.; Gibson, H. W. Polymers from Reissert Compounds.  8:  Synthesis and Polymerization of Difunctional Reissert Compound Monomers of the AB Type from Functionalized Acid Chlorides, Polymer Commun. 1991, 32, 134-136.

117. Gibson, H. W.; Guilani, B.; Rasco, M. L. Synthesis of AA Difunctional Monomers from Bis(isoquinolines), Macromolecules 1991, 24, 3700-3703.

118. Wu, C.; Bheda, M. C.; Lim, C.; Shen, Y. X.; Sze, J.; Gibson, H. W. Synthesis of Polyester Rotaxanes via the Statistical Threading Method, Polymer Commun. 1991, 32, 204-207.

119. Jois, Y. H. R.; Gibson, H. W. Acyclic Polymeric Reissert Compounds:  Chemically Reactive Polyamides, Polymer Commun. 1991, 32, 168-170.

120. Gibson, H. W.; Bheda, M.; Engen, P. T.; Shen, Y. X.; Sze, J.; Wu, C.; Joardar, S.; Ward, T. C.; Lecavalier, P. R. New Polymer Architectures: Polyrotaxanes, Makromol. Chem., Macromol. Symp. 1991, 42/43, 395-407.

121. Bheda, M. C.; Gibson, H. W. Model Studies of End Capping of Mono- and Bi-ended Polystyrene Anions; Stereoisomerism at the Chain Ends, Macromolecules 1991, 24, 2703-2708.

122. Delaviz, Y.; Gibson, H. W. Synthesis of Bis(meta-phenylene)-32-crown-10 Derivatives, Org. Prep. Proc. Int. 1991, 23, 382-385.

123. Gibson, H. W.; Guilani, B. Polymers from Reissert Compounds 6.  Synthesis of Poly(Heteroarylene Ether Ketones) Containing 1,4-Isoquinolinediyl Units, Polymer Commun. 1991, 32, 324-328.

124. Jois, Y. H. R.; Berg, M. A. G.; Merola, J. S.; Gibson, H. W. X-ray Crystal Structure and Reactions of 2-Cyano-1,3-dibenzoyl-2,3-dihydrobenzimidazole, a Novel Reissert Compound, Tetrahedron Lett. 1991, 32, 2997-3000.

125. Grisle, R. A.; Guilani, B.; Gibson, H. W. Unusual Polyester Containing Isoquinoline Nucelei, J. Natl. Tech. Assoc. Spring 1991, 45.

126. Brumfield, K.; Rasco, M. L.; Guilani, B.; Gibson, H. W. Novel Monomers for Poly(heteroarylene ethers), J. Natl. Tech. Assoc. Spring 1991, 48.

127. Wu, C.; Lecavalier, P. R.; Shen, Y. X.; Gibson, H. W. Synthetic Approach to a Rotaxane Via the Template Method, Chem. Materials 1991, 3, 569-572.

128. Delaviz, Y.; Shen, Y. X.; Gibson, H. W. Synthesis of Bis(1,4-Phenylene)-32-Crown-4 and Bis(1,3-Phenylene)-30-Crown-4, Polymer 1992, 33, 212-213.

129. Delaviz, Y.; Gibson, H. W. Macrocyclic Polymers. 1.  Synthesis of a Polyester Crown Based on Bis(5-carboxy-1,3-phenylene)-32-crown-10  and 4,4'-Isopropylidenediphenol (Bisphenol-A), Macromolecules 1992, 25, 18-20.

130. Berg, M. A. G.; Gibson, H. W. Cyanoacylation of 1-Substituted Isoquinolines and 3,4-Dihydroisoquinolines, J. Org. Chem. 1992, 57, 748-750.

131. Shen, Y. X.; Gibson, H. W. Synthesis and Some Properties of a Polyrotaxane Comprised of a Polyurethane Backbone and 60-Crown-20, Macromolecules 1992, 25, 2058-2059.

132. Shen, Y. X.; Engen P. T.; Berg, M. A. G.; Merola, J. S.; Gibson, H. W. Difunctional Paraquat Dictations and Their Crown Complexes: A New Class of Rotaxane Monomers, Macromolecules 1992, 25, 2786-2788.

133. Gibson, H. W.; Engen, P. T., Shen, Y. X., Sze, J., Lim, C., Bheda, M.; Wu, C. Polyrotaxanes: Synthetic Methodologies & Characterization, Makromol. Chem., Macromol. Symp. 1992, 54/55, 519-529.

134. Gibson, H. W.; Pandya, A.; Rasco, M. L.; Guilani, B.; Hermann, C. K. F.; Leblanc, J.-P.;  Jois, Y. H. R. New Step Growth Polymers via Reissert Compound Chemistry, Makromol. Chem., Macromol. Symp. 1992, 54/55, 413-421.

135. Delaviz, Y.; Gibson, H. W. Macrocyclic Polymers. 2. Synthesis of Poly(amide crown)s Based on Bis(5-carboxy-1,3-phenylene)-32-crown-10.  Network Formation Through Threading, Macromolecules 1992, 25, 4859-4862.

136. Jois, Y. H. R.; Gibson, H. W. Bifunctional Heterocycles: A Convenient One Pot Synthesis of Novel Bis(benzoxazoles) from Bis(o-aminophenols), J. Heterocyclic Chem. 1992, 29, 1365-1368.

137. Leblanc J.-P.; Gibson, H. W. Synthesis of a-Aminonitriles by Self-catalyzed, Stoichiometric Reaction of Amines, Aldehydes and Trimethylsilyl Cyanide, Tetrahedron Lett. 1992, 33, 6295-6298.

138. Leblanc, J.-P.; Jois, Y. H. R.; Gibson, H. W. Acyclic Polymeric Reissert Compounds:  Chemically Reactive Polyamides, Part 2., Macromolecules 1992, 25, 6752-6755.

139. Delaviz, Y.; Gungor, A.; McGrath, J. E.; Gibson, H. W. Phosphine Oxide Containing Aromatic Polyester, Polymer 1992, 33, 5346-5347.

140. Berg, M. A. G.; Gibson, H. W. Chromatographic Resolution of Enantiomers on Polyamides Containing 1,2-Disubstituted Cyclohexane Moiety as a Chiral Residue, Chemtracts 1992, 3, 272-275.

141. Delaviz, Y.; Gungor, A.; McGrath, J. E.; Gibson, H. W. Soluble Phosphine Oxide Containing Aromatic Polyamides, Polymer1993, 34, 210-213.

142. Ganguly, S.; Gibson, H. W. Synthesis of a Novel Macrocyclic Arylene Ether Sulphone, Macromolecules 1993, 26, 2408-2412.

143. Pandya, A.; Gibson, H. W. Synthesis and Stereochemistry of Reissert Compounds from Benzothiazole, J. Org. Chem. 1993, 58, 2851-2855.

144. Gibson, H. W.; Lee, S. H.; Engen, P. T.; Lecavalier, P.; Sze, J.; Shen, Y. X.; Bheda, M. New Triarylmethyl Derivatives, Blocking Groups for Rotaxanes and Polyrotaxanes, J. Org. Chem. 1993, 58, 3748-3756.

145. Gibson, H. W.; Engen, P. Rotaxanes Based on Polyacrylonitrile, New. J. Chem. 1993, 17, 723-727.

146. Leblanc, J. P.; Gibson, H. W. Acyclic Polymeric Reissert Compounds: Chemically Reactive Polyamides, Part 3, Macromolecules 1993, 26, 4953-4955.

147.Jois, Y. H. R.; Gibson, H. W. Poly(isoquinoline Reissert Compound)s:  Chemically Reactive Polyamides.  Part 4, Macromolecules 1993, 26, 6151-6154.

REVIEWS, BOOKS, BOOK CHAPTERS

5. Duke, C. B.; Gibson, H. W. Conductive Polymers in Encyclopedia of Semiconductor Technology, M. Grayson, Ed., John Wiley and Sons, New York, N.Y., 1984, pp. 661-699 (Invited).

6. Gibson, H. W. Control of Electrical Properties of Polymers by Chemical Modification (review, 36 figures), Polymer 1984, 25, 3-27.

7. Gibson, H. W.; Pochan, J. M. Acetylenic Polymers, in Encyclopedia of Polymer Science and Engineering, John Wiley and Sons, New York, N.Y., 1984, Vol. 1, pp. 87-130 (Invited).

8. Duke, C. B.; Gibson, H. W. Polymers, Conductive, Kirk Othmer Concise Encyclopedia of Chemical Technology, M. Grayson, Ed., J. Wiley and Sons, New York, NY, 1985, 935 (Invited).

9. Gibson, H. W. Substituted Polyacetylenes, in Handbook on Conducting Polymers, T. Skotheim, Ed., M. Dekker, New York, N.Y., 1986, Vol. 1, pp. 405-439 (Invited).

10. Gibson, H. W., and Pochan, J. M., Acetylenic Polymers in Electrical and Electronic Properties of Polymers: A State-of-the-Art Compendium, J. Wiley and Sons, New York, 1988, pp.1-44. (Invited)

PREPRINTS, UNREFEREED PUBLICATIONS

19. Erhardt, P.; Gibson, H.; Pochan, J.; Pochan, D.; Bailey, F. Sulfonated Encapsulated Toner Compositions, Xerox Disclosure J., 1984, 9, 91.

20. Gibson, H. W.; Weagley, R. J.; Prest, W. M., Jr.; Kaplan, S.; Mosher, R. A.; Epstein, A. J. Kinetics, Mechanisms and Consequences of the Thermal Isomerization of cis-Polyacetylene to trans-Polyacetylene, Preprints, IUPAC Symposium on the Characterization and Analysis of Polymers, Melbourne, Australia, February 11-14, 1985, p. 344.

21. Gibson, H. W.; Weagley, R. J. Approaches to New Substituted Polyacetylenes, Preprints, IUPAC Symposium on the Characterization and Analysis of Polymers, Melbourne, Australia, February 11-14, 1985, p. 347.

22. Gibson, H. W., Pandya, A.; Guilani, B. Heterocyclic Polymers via Reissert Chemistry, Polymer Preprints, 1988, 29(1), 154.

23. Gibson, H. W., Engen, P.; Lecavalier, P. Synthesis of Polyrotaxanes, Polymer Preprints, 1988, 29(1), 248.

PATENTS

13. L. T. Calcaterra and H. W. Gibson, Sterilization Method Using a Sustained Release Disinfectant, U. S. Patent 4,717,544 (1988).

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1974-1983

REFEREED PUBLICATIONS

17. Gibson, H. W.; Pochan, J. M.; Hinman, D.  Effect of Cholesteryl Alkanoate Structure on the Pitch of the Cholesteric Mesophase, in Liquid Crystals and Ordered Fluids, Vol. 2, Plenum Press, New York, 1974, 593-606.

18. Gibson, H. W.  Synthesis of Some New Cholesteryl Esters of Chiral Alkanoic Acids, Mol. Cryst. Liq. Cryst.1974, 27, 43-53. DOI: 10.1080/15421407408083119.

19. Gibson, H. W.; Popp, F. D.  Reissert Compound Studies.  Part XXV.  A Novel Reaction with 2-Nitrobenzaldehyde and the Anion of 2-Acetyl-1,2-dihydroisoquinoldonitrile, Heterocycles1974, 2, 5-7.

20. Gibson, H. W.; Bailey, F. C. Linear Free Energy Relationships. II. Synthesis and Spectral Characterization of Some New Solvatochromics: 5'-Substituted-2-hydroxy-4-stilbazole Derivatives, Tetrahedron1974, 30, 2043-2051. DOI:10.1016/S0040-4020(01)97337-5.

21. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. II. Reaction of Poly(vinylbenzyl Chloride) and Phenols, J. Polym. Sci., Polym. Chem. Ed.1974, 12, 2141-2143.

22. Pochan, J. M.; Gibson, H. W.  The Effect of Structure on the Mesomorphic Properties of Cholesteryl Alkanoates.  V.  Electric Field Effects on a Uniaxial Smectic Phase of Mixtures of Cholesteryl Alkanoates, J. Phys. Chem.1974, 78, 1740-1743. DOI: 10.1021/j100610a012. http://pubs.acs.org/cgi-bin/archive.cgi/jpchax/1974/78/i17/pdf/j100610a012.pdf.

23.Gibson, H. W. Chemical Modification of Polymers. III. An Unusually Facile Displacement Reaction Involving the Anion of a Reissert Compound, Macromolecules1974, 7, 711-712. DOI: 10.1021/ma60041a031. http://pubs.acs.org/cgi-bin/archive.cgi/mamobx/1974/7/i05/pdf/ma60041a031.pdf.

24. Gibson, H. W. Chemical Modification of Polymers. IV. Another Example of Facile Nucleophilic Attack on a Polymer by a Reissert Anion, Macromolecules1975, 8, 89-90. DOI: 10.1021/ma60043a025. http://pubs.acs.org/cgi-bin/archive.cgi/mamobx/1975/8/i01/pdf/ma60043a025.pdf.

25. Kuder, J. E.; Gibson, H. W.; Wychick, D. Electrochemical Characterization of Salicyladehyde Anils, J. Org. Chem.1975, 40, 875-879. DOI: 10.1021/jo00895a013. http://pubs.acs.org/cgi-bin/archive.cgi/joceah/1975/40/i07/pdf/jo00895a013.pdf.

26. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. V. Oxidation of Poly(vinylbenzyl chloride) to Poly(vinylbenzaldehyde), J. Polym. Sci., Polym. Chem. Ed.1975, 13, 1951-1955.

27. Gibson, H. W.; Bailey, F. C. Linear Free Energy Relationships. IV. Synthesis and Spectral Characterization of Some New Solvatochromics.  N-(p-Substituted)benzyl 2'-Hydroxy-4-stilbazolium Betaines, Can. J. Chem.1975, 53, 2162-2070.

28. Gibson, H. W. Linear Free Energy Relationships. V. Triboelectric Charging of Organic Solids, J. Amer. Chem. Soc. 1975, 97, 3832-3833. DOI: 10.1021/ja00846a053. http://pubs.acs.org/cgi-bin/archive.cgi/jacsat/1975/97/i13/pdf/ja00846a053.pdf

29. Gibson, H. W.; Bailey, F. C. Linear Free Energy Relationships. VI. Acidity of N-Methyl 5'-Substituted-2'-hydroxyl-4-stilbazolium Iodides, J. Chem. Soc., Perkin Trans. II1976, 196-203. DOI: 10.1039/P29760000196.

30.Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. VI. Displacement of Reactive Halogens by Isoquinoline Reissert Compound Anions, Macromolecules1976, 9, 10-15. DOI: 10.1021/ma60049a003. http://pubs.acs.org/cgi-bin/archive.cgi/mamobx/1976/9/i01/pdf/ma60049a003.pdf.

31. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. VII. Condensation of Polymeric Aldehydes with the Anion of an Isoquinoline Reissert Compound, J. Polym. Sci., Polym. Chem. Ed.1976, 14, 1661-1669.

32. Gibson, H. W.; Bailey, F. C. Synthesis of Some New Hindered Biaryls, J. Org. Chem.1976, 41, 557-560. DOI: 10.1021/jo00865a033. http://pubs.acs.org/cgi-bin/archive.cgi/joceah/1976/41/i03/pdf/jo00865a033.pdf.

33. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. VIII. Reaction of Quinoline Reissert Compounds (1-Acyl-1,2-dihydroquinaldonitriles) with Polymeric Halides and Aldehydes, Macromolecules1976, 9, 221-226. DOI: 10.1021/ma60050a008. http://pubs.acs.org/cgi-bin/archive.cgi/mamobx/1976/9/i02/pdf/ma60050a008.pdf.

34. Gibson, H. W.; Bailey, F. C. Linear Free Energy Relationships. VII. Synthesis of Properties of a Novel 'Double-Barrelled' Solvatochromic Compound, J. Chem. Soc., Perkin Trans. II1976, 1575-1578. DOI: 10.1039/P29760001575.

35. Gibson, H. W. The Effect of Structure on the Mesomorphic Properties of Cholesteryl Alkanoates. VI. Effect of Configuration in Chiral Alkanoates, J. Phys. Chem.1976, 80, 1310-1314.

36. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers.  IX. Attack of Nitrogen Anions on Poly(vinylbenzyl Chloride), Macromolecules1976, 9, 688-690.

37. Gibson, H. W.; Bailey, F. C.  Synthesis and Polymerization of Some New Carbazole and Phthalimide Monomers, Macromolecules1977, 10, 602-604.

38. Szyper, M.; Zuman, P.; Gibson, H. W.  Polarography and Solvatochromism.  Comparison of Electrochemical and Spectral Properties of 5'-Methoxy-2-hydroxy-N-methyl-4-stilbazolium Iodide, J. Chem. Soc., Far. Trans. I1977, 73, 1032-1038.

39. Gibson, H. W. Linear Free Energy Relationships. VIII. Ionization Potentials of Aliphatic Compounds, Can. J. Chem.1977, 55, 2637-2641.

40. Gibson, H. W.; Bailey, F. C. Linear Free Energy Relationships. IX. Triboelectric Charging of Poly(olefins), Chem. Phys. Lett.  1977, 51, 352-355.

41. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. X. Borohydride Reducing Agents Derived from Anion Exchange Resins, J. Chem. Soc., Chem. Comm.1977, 815.

42. Pochan, J. M.; Gibson, H. W.; Froix, M. F.; Hinman, D. F. Dielectric Relaxations in Solid Solutions of Bis(phenol)-A Diphenyl Carbonate and Lexan Polycarbonate, Macromolecules1978, 11, 165-171.

43. Salaneck, W. R.; Paton, A.; Gibson, H. W.  Electron Spectroscopy for Chemical Analysis:  Applications to Materials for Electrophotography, Inst. Electrical Electronics Eng., Trans. Ind. Appl.1978, A-14, 443-447.

44. Salaneck, W. R.; Gibson, H. W.; Bailey, F. C.; Pochan, J. M.; Thomas, H. R.  Molecular Orientation at the Surface of an Ion Exchanged Sulfonated Polystyrene, J. Polym. Sci., Polym. Letters Ed.1978, 16, 447-452.

45. Gibson, H. W.; Bailey, F. C.; Chu, J. Y. C.; Chemical Modification of Polymers, XI.  XI.  Photoreactive Polymers from Poly(vinylbenzyl chloride), J. Polym. Sci., Polym. Chem. Ed.1979, 17, 777-782.

46. Gibson, H. W.; Bailey, F. C.; Pochan, J. M.  Synthesis and Thermal Characterization of Some Novel Phenol Carbonates, J. Polym. Sci., Polym. Chem. Ed.1979, 17, 2499-2509.

47. Gibson, H. W.; Bailey, F. C.; Mincer, J. L.; Gunther, W. H. H. Chemical Modification of Polymers. XII. Control of Triboelectric Charging Properties of Polymers by Chemical Modification, J. Polym. Sci., Polym. Chem. Ed.1979, 17, 2961-2974.

48.Gibson, H. W.; Pochan, J. M.; Bailey, F. C.  Surface Analyses by a Tribolelectric Charging Technique, Anal. Chem.1979, 51, 483-487.

49. Pochan, J. M.; Gibson, H. W.; Bailey, F. C.; Pochan, D. F. Space Charge Effects of Semiconductive Coatings on Triboelectric Charge Exchange, J. Electrostatics1980, 8, 183-194.

50. Bigelow, R. W.; Pochan, J. M.; Bailey, F. C.; Salaneck, W. R.; Thomas, H. R.; Pochan, D. F.; Gibson, H. W.  Structure Variation of Sulfonated Polystyrene Surfaces, Advances in Chemistry1980, 187, 295-308.

51. Gibson, H. W.; Bailey, F. C. Chemical Modification of Polymers. XIII.  Sulfonation of Polystyrene Surfaces, Macromolecules1980, 13, 34-41.

52. Pochan, J. M.; Gibson, H. W.; Bailey, F. C.; Pochan, D. F. Oxygen Doping of Polyacetylene as Determined via Dielectric Techniques, Polymer1980, 21, 250-251.

53. Pochan, J. M.; Gibson, H. W.; Bailey, F. C.  Oxygen Doping of Polyacetylene, J. Polym. Sci., Polym. Lett. Ed.1980, 18, 447-451.

54. Gibson, H. W.; Bailey, F. C.; Epstein, A. J.; Rommelmann, H.; Pochan, J. M.  A New Free-Standing Dopable Electrically Conducting Polyene Film, J. Chem. Soc., Chem. Comm.1980, 426.

55. Epstein, A. J.; Gibson, H. W.; Chaikin, P. M.; Clark, W. G.; Gruner, G.  Frequency and Electric Field Dependent Conductivity of Metallic Polyacetylene, Phys. Rev. Lett.1980, 45, 1730-1733.

56. Gibson, H. W.; Bailey, F. C.  Chemical Modification of Polymers, 17.  Dyeing of Sulfonated Polystyrene Films by Ion Exchange with Cationic Dyes, Polymer1981, 22, 1068-1072.

57. Pochan, J. M; Pochan, D. F.; Gibson, H. W.  The Kinetics of Oxygen Doping and Oxidation of Poly(1,6-heptadiyne), Polymer1981, 22, 1367-1372.

58. Pochan, J. M.; Pochan, D. F.; Rommelmann, H.; Gibson, H. W. Kinetics of Doping and Degradation of Polyacetylene by Oxygen, Macromolecules1981, 14, 110-114.

59. Gibson, H. W.; Olin, G. R.; Pochan, J. M. Linear Free Energy Relationships. X.  Synthesis, Thermal, Electrochemical and Hole Transport (Conduction) Properties of Some Novel Carbazole Derivatives, J. Chem. Soc.,Perkin II1981, 1267-1273.

60. Gibson, H. W.; Pochan, J. M.; Kaplan, S.  13C Magic Angle NMR Study of the Isomerization of Cis- to Trans-Polyacetylene, J. Am. Chem. Soc.1981, 103, 4619-4620.

61. Epstein, A. J.; Rommelmann, H.; Gibson, H. W.  Conducting Polymers: Polyacetylene, Mat. Sci.1981, 7, 133-142.

62. Epstein, A. J.; Gibson, H. W.; Chaikin, P. M.; Clark, W. G.; Gruner, G.  Electric Field Dependent Conductivity of Metallic Polyacetylene, Chimica Scripta1981, 17, 135-136.

63. Epstein, A. J.; Rommelmann, H.; Abkowitz, M.; Gibson, H. W. Frequency Dependent Conductivity of Polyacetylene, Mol. Cryst. Liq. Cryst.1981, 77, 81-96.

64. Rommelmann, H.; Fernquist, R.; Gibson, H. W.; Epstein, A. J.; Druy, M. A.; Woerner, T.  Morphology and Dopant Distribution in (CH)x, Mol. Cryst. Liq. Cryst.,1981, 77, 177-184.

65. Epstein, A. J.; Rommelmann, H.; Abkowitz, M.; Gibson, H. W. Anomalous Frequency Dependent Conductivity of Polyacetylene, Phys. Rev. Lett.1981, 47, 1549-1553.

66. Pochan, J. M.; Harbour, J.; Gibson, H. W.  The Effect of a Free Radical Quencher on the Intrinsic Conductivity, Oxidative Stability and Free Radical Population of Poly(1,6-heptadiyne), Polymer1982, 23, 435-438.

67. Pochan, J. M.; Harbour, J.; Gibson, H. W.  Effects of Oxidation on I2 Doping of Trans-Polytacetylene as Studied Via ESR and Conductivity Measurements, Polymer1982, 23, 439-444.

68. Pochan, J. M.; Gibson, H. W.  Dye Sensitization of Poly(N-vinylcarbazole) by Sulfonation and Ion Exchange, J. Polym. Sci., Polym. Phys. Ed.1982, 20, 2059-2067.

69. Hoffman, D. M.; Tanner, D. B.; Epstein, A. J.; Gibson, H. W. Far Infrared Absorption in (CH)x Below the Non-metal-Metal Transition, Mol. Cryst. Liq. Cryst.1982, 83, 1175-1182.

70. Gibson, H. W.; Pochan, J. M.  Chemical Modification of Polymers, 19. Oxidation of Polyacetylene, Macromolecules1982, 15, 242-247.

71. Epstein, A. J.; Rommelmann, H.; Fernquist, R.; Gibson, H. W.; Druy, M. A.; Woerner, T.  Morphology of Polyacetylene and Doped Polyacetylene, Polymer1982, 23, 1211-1221.

72. Pochan, J. M.; Gibson, H. W.; Pochan, D. F.  Dielectric Relaxation Studies on Bis(phenol-A) Bis(cumylphenyl) Carbonate/Lexan Polycarbonate Solid Solutions, Macromolecules1982, 15, 1368-1372.

73. Salaneck, W. R.; Gibson, H. W.; Plummer, E. W.; Tonner, B. H. Ultraviolet Photoelectron Spectroscopy of Optically Excited States in Trans-polyacetylene, Phys. Rev. Lett.1982, 45, 801-804.

74. Hoffman, D. M.; Gibson, H. W.; Epstein, A. J.; Tanner, D. B. Conversion of Cis-Polyacetylene to Trans-Polyacetylene During Doping, Phys. Rev. B.1983, 27, 1454-1457.

75. Robin, P.; Pouget, J. P.; Comes, R.; Gibson, H. W.; Epstein, A. J.  Structural Study of the Cis to Trans Thermal Isomerization of Polyacetylene, Phys. Rev. B.1983, 27, 3938-3941.

76. Andres, J. R.; Orlowski, T. E.; Gibson, H. W.; Slade, M. L. Hot Luminescence in Trans-Polyacetylene:  A Picosecond Time Resolved Study, Phys. Rev. B.1983, 27, 6545-6548.

77. Epstein, A. J.; Rommelmann, H.; Bigelow, R.; Gibson, H. W.; Hoffman, D. M.; Tanner, D. B.  Role of Solitons in Nearly Metallic Polyacetylene, Phys. Rev. Lett.1983, 50, 1866-1869.

78. Epstein, A. J.; Rommelmann, H.; Bigelow, R.; Gibson, H. W.; Hoffman, D. M.; Tanner, D. B.  Coordinated Study of Nearly Metallic Polyacetylene: Role of Solitons, J. Physique1983, 44 (6), C-3, 61-68.

79. Robin, P.; Pouget, J. P.; Comes, R.; Gibson, H. W.; Epstein, A. J.  Structural Study of the Cis-to-Trans Thermal Isomerization in Polyacetylene, J. Physique1983, 44 (6), C-3, 77-81.

80. Robin, P.; Pouget, J. P.; Comes, R.; Gibson, H. W.; Epstein, A. J.  X-Ray Diffraction Studies of Iodine Doped Polyacetylene, J. Physique1983, 44 (6), C-3, 87-92.

81. Gibson, H. W.; Weagley, R. J.; Prest, Jr. W. M.; Mosher, R.; Kaplan, S. Cis-Trans Isomerization of Polyacetylene, J. Physique1983, 44(6), C-3, 123-126.

82. Sokol, P. E.; Gaines, J. R.; Cho, S. J.; Tanner, D. B.; Gibson, H. W.; Epstein; A. J.  Frequency and Temperature Dependence of 1H NMR T1 of Trans-(CH)x, J. Physique1983, 44(6), C-3, 349-352.

83. Gibson, H. W.; Epstein, A. J.; Rommelmann, H.; Tanner, D. B.; Yang, X. Q.; Pochan, J. M.  Substituted Polyacetylenes by Cyclopolymerization: Poly(1,6-heptadiyne) and Poly(propiolic anhydride), J. Physique1983, 44(6), C-3, 651-656.

84. Gibson, H. W.; Bailey, F. C.; Epstein, A. J.; Rommelmann, H.; Kaplan, S.; Harbour, J.; Yang, X.; Tanner, D. B.; Pochan, J. M.  Poly(1,6-heptadiyne), A Free-standing Polymer Film Dopable to High Electrical Conductivity, J. Am. Chem. Soc.1983, 105, 4417-4431.

85. Pochan, J. M.; Gibson, H. W.  Barrier Activated I2 Doping of Trans-Polyacetylene as Studied by ESR, Polym. Comm.1983, 24, 322-323.

86. Gibson, H. W.  Dyed Sulfonated Polystyrene Films: Relationship of Triboelectric Charging and Molecular Orbital Energy Levels, in Modification of Polymers, C. E. Carraher, Jr. and J. A. Moore, Eds., Plenum Pub. Corp., New York, N.Y., 1983, 353-372 (Invited).

87. Robin, P.; Pouget, J. P.; Comes, R.; Gibson, H. W.; Epstein, A. J.  X-Ray Diffraction Studies of Iodine Doped Polyacetylene, Polymer1983, 24, 1558-1564.

88. Epstein, A. J.; Rommelmann, H.; Bigelow, R.; Gibson, H. W.; Hoffman, D. M.; Tanner, D. B.  Reply to Comment on 'Role of Solitons in Nearly Metallic Polyacetylene', Phys. Rev. Lett.1983, 51, 2020.

REVIEWS, BOOKS, BOOK CHAPTERS

2. Gibson, H. W. Cholestric Mesophases, Chap. in Liquid Crystals, the Fourth State of Matter, F. D. Saeva, Ed., M. Dekker, Inc., N.Y., 1979, pp. 99-162 (Invited).

3. Gibson, H. W.; Pochan, J. M. Study Guide to Introduction to Polymer Chemistry, American Chemical Society, 1981, Washington, D. C. (56 pages).

4. Duke, C. B.; Gibson, H. W. Conductive Polymers, Kirk-Othmer Encyclopedia of Chemical Technology, J. Wiley and Sons, N.Y., Vol. 18, 1982, pp. 755-794 (Invited).

PREPRINTS, UNREFEREED PUBLICATIONS

1. Gibson, H. W.; Chu, J. Y. C. Photosensitive Polymers, Xerox Disclosure J. 1977, 2, 21.

2. Gibson, H. W.; Salaneck, W. R.; Bailey, F. C.; Pochan, J. M.; Thomas, H. R. Molecular Orientation at the Surface of an Ion Exchanged Sulfonated Polystyrene, Polym. Prepr. 1978, 19(2), 320.

3. Chu, J. Y. C.; Gibson, H. W. Photosensitive Polymers, Xerox Disclosure J. 1979, 4, 573.

4. Pochan, J. M.; Gibson, H. W. Effects of Oxygen Upon the Conductivity of Polyacetylene, A. C. S. Org. Coatings Plast. Chem. 1980, 42, 600.

5. Gibson, H. W.; Bailey, F.C.; Pochan, J. M.; Epstein, A. J.; Rommelmann, H. New Free-Standing Conductive Substituted Polyacetylene Film, A. C. S. Org. Coatings Plast. Chem.1980, 42, 603.

6. Pochan, J. M.; Epstein, A. J.; Gibson, H. W. Chemical Modification of Conductive Polymers, Electrochem. Soc. Ext. Abstr., 1980, 80-1, 165.

7. Gibson, H. W.; Bailey, F. C.; Rommelmann, H. R.; Epstein, A. J.; Pochan, J. M. Synthesis, Characterization and Doping of a Substituted Polyacetylene, A. C. S. Org. Coatings Plast. Chem. 1980, 43, 860.

8. Pochan, J. M.; Gibson, H. W. Effect of Free Radicals (Solitons) on the Kinetics of Oxidation and Doping of Polyenes, A. C. S. Org. Coatings Plast. Chem. 1980, 43, 872.

9. Gibson, H. W.; Bailey, F. C.; Pochan, J. M.; Harbour, J. The Cyclopolymer Poly(1,6-heptadiyne): Doping and Oxidation, Polym. Prepr. 1981, 22(1), 35.

10. Gibson, H. W.; Bailey, F. C.; Pochan, J. M.; Harbour, J. The Cyclopolymer Poly(1,6-heptadiyne): Doping and Oxidation, A. C. S. Org. Coatings Plast. Chem., 1981, 44, 462.

11. Pochan, J. M.; Gibson, H. W.; Bailey, F. C. Sulfonated Tower Compositions, Xerox Disclosure J., 1981, 6, 393.

12. Gibson, H. W. Dyed Sulfonated Polystyrene Films as Probes of Molecular Basis of Triboelectric Charging, A. C. S. Org. Coatings, Plast. Chem., 1982, 46, 436.

13. Epstein, A. J.; Rommelmann, H.; Abkowitz, M.; Gibson, H. W. Frequency Dependence of Conductivity: Applications to Conducting Polymers, Polym. Prepr. 1982, 23, 88.

14. Kaplan, S.; Gibson, H. W.; Mosher, R. S.; Prest, W. M., Jr. A Solid State Carbon-13 Nuclear Magnetic Resonance and Infrared Investigation of Isomerization of Polyacetylene, Proc. IUPAC 28th Macromol. Symp., Amherst, MA, July 12-16, 1982, p. 16.

15. Gibson, H. W.; Pochan, J. M. New Conducting Polymers, Proc. IUPAC 28th Macromol. Symp., Amherst, MA, July 12-16, 1982, p. 406.

16. Pochan, J. M.; Gibson, H. W. Chemical Stability of Polyacetylene and Poly(1,6-heptadiyne), Proc. IUPAC 28th Macromol. Symp., Amherst, MA, July 12-16, 1982, p. 414.

17. Epstein, A. J.; Rommelmann, H.; Kaufer, J. W.; Gibson, H. W. Charge Transport Studies of Conducting Polymers, Proc. IUPAC 28th Macromol. Symp., Amherst, MA, July 12-16, 1982, p. 420.

18. Gibson, H. W.; Prest, W. M.; Mosher, R. A.; Kaplan, S.; Weagley, R. J. Thermal Isomerization of Polyacetylene Films, Polym. Prepr. 1983, 24(2), 153.

PATENTS

1. H. W. Gibson and F. D. Saeva, Electrostatographic Carrier Composition, U.S. Patent 4,043,929 (1977).

2. H. W. Gibson and F. D. Saeva, Tribo Modified Toner Materials Via Silylation and Electrostatographic Imaging Process, U.S. Patent 4,070,186 (1978).

3. H. W. Gibson and W. H. H. Gunther, Triboelectrically Controlled Covalently Dyed Toner Materials, U.S. Patent 4,070,296 (1978).

4. H. W. Gibson, F. C. Bailey and J. L. Mincer, Tribo Modified Carrier Materials via Acylation, U.S. Patent, 4,076,893 (1978).

5. H. W. Gibson and W. H. H. Gunther, Imaging Method Utilizing Functionalized Carrier Materials, U.S. Patent, 4,078,926 (1978).

6. H. W. Gibson and W. H. H. Gunther Aminolyzed Toner Compositions and Imaging Process Using Same, U.S. Patent 4,078,931 (1978).

7. H. W. Gibson and W. H. H. Gunther, Aminolyzed Carrier Coatings, U.S. Patent 4,079,166 (1978).

8. H. W. Gibson and F. D. Saeva, Imaging Process Utilizing Silylated Coated Carriers, U.S. Patent 4,092,163 (1978).

9. H. W. Gibson and W. H. H. Gunther, Developer Composition Comprising Aminolyzed Carrier Coatings, U.S. Patent 4,094,803 (1978).

10. H. W. Gibson, F. C. Bailey and J. L. Mincer, Tribo Modified Toner Materials via Acylation, U.S. Patent 4,134,760 (1979).

11. J. L. Mincer, H. W. Gibson and F. C. Bailey, Triboelectric Modified Carrier for Electrostatographic Developer, U.S. Patent 4,152,279 (1979).

12. H. W. Gibson, F. C. Bailey and J. L. Mincer, Carrier Coated with Acyl Modified Styrene Copolymer, Used in Electrostatic Imaging Process, U.S. Patent 4,156,607 (1979).

Foreign Patents

1. H. W. Gibson, Electrostatographic Developer Mixture Containing Fine Particles of Systematically Halogenated, Acylated, Alkylated, or Nitrated-Oxidized Aromatic Polymer, German Offen. 252993 (1976).

2. H. W. Gibson and W. H. H. Gunther, Electrostatographic Toner Mixture - Containing Fine Toner Particles Consisting of Activated Polymer Containing Covalently Bonded Active Dye Groups, German Offen. 2,537,132 (1976).

3. H. W. Gibson and W. H. H. Gunther, Electrostatographic Toner Mixture - Containing Fine Toner Particles Consisting of Activated Polymer Containing Covalently Bonded Active Dye Groups, Netherlands Patent 7,510,079 (1976).

4. H. W. Gibson, Electrostatographic Developer Mixture Containing Fine Particles of Systematically Halogenated, Acylated, Alkylated or Nitrated - Oxidized Aromatic Polymer, Netherlands Patent 7,510,081 (1976).

5. H. W. Gibson and F. D. Saeva, Electrostatic Developers, Netherlands Patent 7,510,082 (1976).

6. H. W. Gibson, F. C. Bailey and J. Mincer, Electrostatographic Developer Mixture - Containing Fine Activated Polymer Particles Obtained by Acylating Hydroxyl or Amino Groups in Initial Polymer, Netherlands Patent 7,510,083 (1976).

7. H. W. Gibson and W. H. H. Gunther, Electrostatographic Developer Mixture - Containing Fine Activated Polymer Particles Obtained by Aminolysis of Ester Groups in Initial Polymer, Netherlands Patent 7,510,084 (1976).

8. H. W. Gibson and W. H. H. Gunther, Tribolelectrically Controlled Covalently Dyed Toner Materials, British Patent 1,502,817 (1978).

9. H. W. Gibson and W. H. H. Gunther, Electrostatographic Developer Compositions, British Patent 1,525,702 (1978).

10. H. W. Gibson and F. D. Saeva, Electrostatographic Developer Mixtures, British Patent 1,525,703 (1978).

11. H. W. Gibson, Imaging System, British Patent 1,525,704 (1978).

12. H. W. Gibson and F. D. Saeva, Electrostatic Developers, British Patent 1,525,705 (1978).

13.H. W. Gibson, Imaging System, Canadian Patent 1,062,945 (1979).

14. H. W. Gibson and W. H. H. Gunther, Triboelectrically Controlled Covalently Dyed Toner Materials, Canadian Patent 1,067,741 (1979).

15. H. W. Gibson, Imaging System, Canadian Patent 1,073,726 (1980).

16. H. W. Gibson, F. C. Bailey and J. L. Mincer, Imaging System, Canadian Patent 1,077,324 (1980).

17. H. W. Gibson and F. D. Saeva, Imaging System, Canadian Patent 1,077,325 (1980).

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1964-1973

REFEREED PUBLICATIONS

1. Popp, F. D.; Gibson, H. W. Reissert Compound Studies. VI. The Condensation of Aldehydes with 2-Benzoyl-1,2-dihydroisoquinaldonitrile, J. Heterocyclic Chem. 1964, 1, 51-52.

2. Gibson, H. W.; Popp, F. D.; Catala, A. C. Reissert Compound Studies. VII.  The Synthesis of Calycotomine, J. Heterocyclic Chem. 1964, 1, 251-252.

3. Howe, C. A.; Hamel, C. R.; Gibson, H. W.; Flynn, R. R. Orientation in Nitration of Trisubstituted Benzenes, J. Chem. Soc. 1965, 795-797. DOI: 10.1039/JR9650000786.  http://www.rsc.org/ejarchive/JR/1965/JR9650000786.pdf

4. Gibson, H. W.; Popp, F. D.; Noble, A. C.  Reissert Compound Studies.  X.  The Synthesis of Armepavine, J. Heterocyclic Chem., 1966, 3, 99-100.

5. Popp, F. D.; Gibson, H. W.; Noble, A. C.  Reissert Compound Studies.  XII.  Synthesis of O-Methyldauricine, J. Org. Chem. 1966, 31, 2296-2299. DOI: 10.1021/jo01345a050http://pubs.acs.org/cgi-bin/archive.cgi/joceah/1966/31/i07/pdf/jo01345a050.pdf

6. Gibson, H. W.; Popp, F. D.  Reissert Compound Studies.  Part XIII.  Model Reactions Based on 2-Benzoyl-1,2-dihydroisoquinaldonitrile, J. Chem. Soc. 1966, 1860-1864.

7. Gibson, H. W.  Anisochronism of Diastereotopic Groups in 1-Isopropyl- and 1-Isobutyl-2-acyl-1,2-dihydroisoquinaldonitriles, Tetrahedron Lett. 1968, 5549-5551. DOI:10.1016/S0040-4039(00)75558-4

8. Gibson, H. W.; McKenzie, D. A. A Novel Single Step Sulfone Synthesis, J. Org. Chem. 1970, 35, 2994-3002. DOI: 10.1021/jo00834a032. http://pubs.acs.org/cgi-bin/archive.cgi/joceah/1970/35/i09/pdf/jo00834a032.pdf

9. Gibson, H. W. The Isolation and Characterization of Some 1-Alkyl-2-acyl-1,2-dihydroisoquinaldonitriles, J. Heterocyclic, Chem. 1970, 7, 1169-1172. 

10. Pochan, J. M.; Gibson, H. W. Nucleation Studies of Supercooled Cholesteric Liquid Crystals, J. Amer. Chem. Soc. 1971, 93, 1279-1280. DOI: 10.1021/ja00734a050. http://pubs.acs.org/cgi-bin/archive.cgi/jacsat/1971/93/i05/pdf/ja00734a050.pdf

11. Gibson, H. W.; Chesney, D. K.; Popp, F. D. Reissert Compound Studies.  Cyclization of N-(w-Chloroalkanoyl) Reissert Compounds, J. Heterocyclic Chem. 1972, 9, 541-544.

12. Pochan, J. M.; Gibson, H. W. Crystal Nucleation in Supercooled Mesomorphic Phase of Cholestryl Derivatives, J. Am. Chem. Soc. 1972, 94, 5573-5577. DOI: 10.1021/ja00771a007. http://pubs.acs.org/cgi-bin/archive.cgi/jacsat/1972/94/i16/pdf/ja00771a007.pdf

13. Gibson, H. W.; Bailey, F. C. Aminolysis of n-Butyl Methacrylate-Styrene Copolymer with Di- and Trifunctional Amines, J. Polym. Sci., Polym. Chem. Ed. 1972, 10, 3017-3025.

14. Gibson, H. W.; Pochan, J. M.  Effect of Cholesteryl Alkanoate Structure on Liquid Crystal Transition Thermodynamics Pure and In Binary Mixtures, J. Phys. Chem. 1973, 77, 837-845. DOI: 10.1021/j100625a021. http://pubs.acs.org/cgi-bin/archive.cgi/jpchax/1973/77/i06/pdf/j100625a021.pdf.

15. Gibson, H. W. The Stereochemistry of 1-Alkyl-2-acyl-1,2-dihydroisoquinaldonitriles, J. Org. Chem. 1973, 38, 2851-2857. DOI: 10.1021/jo00956a026. http://pubs.acs.org/cgi-bin/archive.cgi/joceah/1973/38/i16/pdf/jo00956a026.pdf

16. Gibson, H. W.  Correlation of Ionization Potentials and the Sums of Substituent Constants for Substituted Benzenes, Can. J. Chem. 1973, 51, 3065-3070.

REVIEWS, BOOKS, BOOK CHAPTERS

1. Gibson, H. W. The Chemistry of Formic Acid and Its Simple Derivatives, Chem. Rev., 1969, 69, 673-692.

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